1,2,4-Benzenetricarboxylic acid

1,2,4-Benzenetricarboxylic acid Basic information
Product Name:1,2,4-Benzenetricarboxylic acid
Synonyms:1,2,4-Benzenetricarboxylic acid,Benzene-1,2,4-tricarboxylic acid, Trimellitic acid;1-2-4-BENZENETRICARBOXYLIC ACIDCRYSTALLI NE;1,2,4-Benzenetricarboxylic acid, 98% 50GR;1,2,4-BENZENETRICARBOXYLIC ACID, 99+%;BENZENETRICARBOXYLICACID;1,2,4-BENZENETRICARBOXYLIC ACID / TRIMELLITIC ACID;Benyop- 1,2,4-Tricarboxybenzene;Benzene-1,2,4-tricarboxylic acid, Trimellitic acid
CAS:528-44-9
MF:C9H6O6
MW:210.14
EINECS:208-432-3
Product Categories:Industrial/Fine Chemicals;MOFS COFS
Mol File:528-44-9.mol
1,2,4-Benzenetricarboxylic acid Structure
1,2,4-Benzenetricarboxylic acid Chemical Properties
Melting point 229-231 °C (dec.) (lit.)
Boiling point 309.65°C (rough estimate)
density 1.4844 (rough estimate)
refractive index 1.6630 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility 2.1g/l
form Crystalline Powder
pkapK1: 2.52;pK2: 3.84;pK3: 5.20 (25°C)
color White
Water Solubility 2.1 G/100 ML (25 ºC)
Merck 14,9702
BRN 2214815
InChIKeyARCGXLSVLAOJQL-UHFFFAOYSA-N
LogP1.240 (est)
CAS DataBase Reference528-44-9(CAS DataBase Reference)
NIST Chemistry Reference1,2,4-Benzenetricarboxylic acid(528-44-9)
EPA Substance Registry System1,2,4-Benzenetricarboxylic acid (528-44-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 2
RTECS DC1980000
Hazard Note Irritant
TSCA Yes
HS Code 29173990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
1,2,4-Benzenetricarboxylic acid Usage And Synthesis
Chemical PropertiesColorless crystals.Partially soluble in DMF and alcohol; insoluble in benzene and carbon disulfide; slightly soluble in water.
UsesIntermediate in the preparation of resins, plasticizers, dyes, inks, adhesives.
Uses1,2,4-Benzenetricarboxylic acid (trimellitic acid) is generally used as carboxylate ligand in the synthesis of a wide range of metal-organic frameworks (MOFs). It can also be used to synthesize Ln3+ encapsulated nanocrystals which exhibit white-light luminescence.
DefinitionChEBI: Benzene substituted at the 1,2, and 4 positions by carboxy groups.
Purification MethodsCrystallise the acid from acetic acid or aqueous EtOH. [Beilstein 9 IV 3746.]
1,2,3-Benzenetricarboxylic acid tri(trimethylsilyl) ester TRIMELLITIC ACID AMIDE TRIMELLITIC ACID TRIMETHYL ESTER BENZENEPENTACARBOXYLIC ACID TRIMELLITIC ACID TRI-N-BUTYL ESTER,TRIMELLITIC ACID TRIBUTYL ESTER 1,2,4-Benzenetricarboxylic acid, mixed hexyl and octyl triesters 1,2,4-Benzenetricarboxylic acid hydrogen 1,4-dimethyl ester Ethyl 2-(Chlorosulfonyl)acetate TRIMELLITIC ACID AMIDE 5G [R] Ascoric Acid TETRAMETHYL PYROMELLITATE Triallyl trimellitate TRIMELLITIC ACID TRIISODECYL ESTER 1,2,4-Benzenetricarboxylic acid Trioctadecyl ester TETRAALLYL PYROMELLITATE Trimellitic acid chloride BENZENEHEXACARBOXYLIC ACID HEXAMETHYL ESTER Trimellitic acid triisononyl ester

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