ChemicalBook Product Catalog Biochemical Engineering Amino Acids and Derivatives Alanine derivatives N-Carbobenzyloxy-L-alanine

N-Carbobenzyloxy-L-alanine

N-Carbobenzyloxy-L-alanine Basic information
Product Name:N-Carbobenzyloxy-L-alanine
Synonyms:N-CBZ-L-ALANINE;N-CBZ-L-ALANINE-OH;N-CARBOBENZYLOXY-L-ALANINE;N-ALPHA-BENZYLOXYCARBONYL-L-ALANINE;N-ALPHA-CARBOBENZOXY-L-ALANINE;N-ALPHA-CBZ-L-ALANINE;N-BENZYLOXYCARBONYL-L-ALANINE;N-CARBOBENZOXY-L-ALANINE
CAS:1142-20-7
MF:C11H13NO4
MW:223.23
EINECS:214-532-8
Product Categories:Alanine [Ala, A];Z-Amino Acids and Derivatives;Amino Acids;Amino Acids (N-Protected);Biochemistry;Cbz-Amino Acids;Protected Amino Acids;PROTECTED AMINO ACID & PEPTIDES;Chiral Compounds;Z-Amino acid series;bc0001
Mol File:1142-20-7.mol
N-Carbobenzyloxy-L-alanine Structure
N-Carbobenzyloxy-L-alanine Chemical Properties
Melting point 84-87 °C
alpha -15 º (c=2, AcOH 24 ºC)
Boiling point 364.51°C (rough estimate)
density 1.2446 (rough estimate)
refractive index -14.5 ° (C=2, AcOH)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
pka4.00±0.10(Predicted)
form Powder
color White
optical activity[α]23/D 14.2°, c = 2 in acetic acid
BRN 2056164
InChIKeyTYRGLVWXHJRKMT-QMMMGPOBSA-N
CAS DataBase Reference1142-20-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 22-24/25-36-26
WGK Germany 3
HazardClass IRRITANT
HS Code 29242990
MSDS Information
ProviderLanguage
N-CBZ-L-Alanine English
SigmaAldrich English
ACROS English
ALFA English
N-Carbobenzyloxy-L-alanine Usage And Synthesis
Chemical Propertieswhite powder
UsesN-Benzyloxycarbonyl-L-alanine is an intermediate in the synthesis of Perindopril (P287500), an angiotensin-converting enzyme (ACE) inhibitor. Antihypertensive.
N-Carbobenzyloxy-L-alanine Preparation Products And Raw materials
Preparation ProductsDELAPRIL-->N-Cbz-D-Alanine-->(S)-4-Methyl-2,5-oxazolidonedione-->Carbamic acid, N-[(1S)-2-(dimethylamino)-1-methyl-2-oxoethyl]-, phenylmethyl ester
N-Carbobenzyloxy-L-glutamine Z-PRO-ONP Phenprobamate carbobenzyloxy-beta-alanine N-Benzyloxycarbonyl-L-asparagine N-Carbobenzyloxy-L-alanine Z-L-PROLINE Trimethoprim Nalpha-Cbz-L-Arginine N-Carbobenzyloxyglycine L-Alanine Z-LYS(Z)-ONP L-Alanine N-Cbz-L-Serine N,N'-Bis(benzyloxycarbonyl)-L-cystine Z-TYR(Z)-OH Z-TYR-ONP N-(tert-Butoxycarbonyl)-L-alanine
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