ChemicalBook Product Catalog Chemical Reagents Organic reagents Sulfone, sulfoxide compound CHLOROMETHYL PHENYL SULFOXIDE

CHLOROMETHYL PHENYL SULFOXIDE

CHLOROMETHYL PHENYL SULFOXIDE Basic information
Product Name:CHLOROMETHYL PHENYL SULFOXIDE
Synonyms:CHLOROMETHYL PHENYL SULFOXIDE;[(chloromethyl)sulphinyl]benzene;[(Chloromethyl)sulfinyl]benzene;Phenyl (chloromethyl) sulfoxide;Benzene, ((chloromethyl)sulfinyl)-;Einecs 230-580-2;Chloromethyl phenyl sulfoxide >=97.0%
CAS:7205-94-9
MF:C7H7ClOS
MW:174.65
EINECS:230-580-2
Product Categories:Organic Building Blocks;Sulfoxides;Sulfur Compounds
Mol File:7205-94-9.mol
CHLOROMETHYL PHENYL SULFOXIDE Structure
CHLOROMETHYL PHENYL SULFOXIDE Chemical Properties
Melting point 33-35 °C
Boiling point 109-111 °C/0.01 mmHg
density 1.35±0.1 g/cm3(Predicted)
Fp 100 °C
storage temp. -20°C
BRN 1617664
EPA Substance Registry SystemBenzene, [(chloromethyl)sulfinyl]- (7205-94-9)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
CHLOROMETHYL PHENYL SULFOXIDE Usage And Synthesis
UsesChloromethyl phenyl sulfoxide has been used in the preparation of:
  • 1-chloroalkyl sulfoxides
  • starting material for the synthesis alkyl sulfoxides and thiol ester acyl anion equivalent
Synthesis Reference(s)Journal of the American Chemical Society, 90, p. 4496, 1968 DOI: 10.1021/ja01018a078
Synthesis, p. 831, 1986
Tetrahedron Letters, 17, p. 613, 1976
General DescriptionChloromethyl phenyl sulfoxide has synthetic potential and exhibits unusual stereochemical specificity. Stereospecific hydroxyalkylation of chloromethyl phenyl sulfoxide has been investigated.
CHLOROMETHYL PHENYL SULFOXIDE Preparation Products And Raw materials
1-CHLORO-2-PHENYLVINYL 4-METHYLPHENYL SULFONE 3,5-BIS(TRIFLUOROMETHYL)PHENYL CHLOROMETHYL SULFONE SPECS AK-823/41252283 Sulfoxide, pentachlorophenyl trichloromethyl 1-chloro-4-[(chloromethyl)sulphonyl]benzene CHLOROMETHYL PHENYL SULFOXIDE CHLOROMETHYL PHENYL SULFONE 1,2-DICHLOROVINYL4-METHYLPHENYLSULFONE 1-[(CHLOROMETHYL)SULFONYL]NAPHTHALENE Phenyl sulfoxide P-TOLUENESULFONYLMETHYL CHLORIDE 4-[2-CHLORO-2-(PHENYLSULFONYL)ETHYL]-1,4-OXAZINAN-4-IUM CHLORIDE [(1-CHLORO-4-PHENYLBUTA-1,3-DIENYL)SULFINYL]BENZENE
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