ChemicalBook Product Catalog Biochemical Engineering Amino Acids and Derivatives Amino alcohol derivative D(-)Prolinol

D(-)Prolinol

D(-)Prolinol Basic information
Product Name:D(-)Prolinol
Synonyms:(+)-D-PROLINOL;D(-)PROLINOL;D-PROLINOL;H-D-PROLINOL;H-D-PRO-OL;(R)-(-)-2-(Hydroxymethyl)pyrrolidine (R)-(-)-2-Pyrrolidinemethanol;(R)-(-)-PyrrolidinemethanolD-Prolinol;D-Pro-ol(oil)
CAS:68832-13-3
MF:C5H11NO
MW:101.15
EINECS:629-147-4
Product Categories:Amino alcohols;Chiral Building Blocks;Proline [Pro, P];Amino Alcohols;Glycidyl Compounds, etc. (Chiral);Synthetic Organic Chemistry;Pharmaceutical Intermediates
Mol File:68832-13-3.mol
D(-)Prolinol Structure
D(-)Prolinol Chemical Properties
alpha -31 º (c=1, toluene)
Boiling point 74-76 °C2 mm Hg(lit.)
density 1.036 g/mL at 20 °C(lit.)
refractive index n20/D 1.485
Fp 187 °F
storage temp. Keep in dark place,Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Methanol (Slightly), Toluene (Slightly)
pka14.77±0.10(Predicted)
form Solution
Specific Gravity1.025
color Clear to slightly hazy colorless to amber
optical activity[α]20/D 31°, c = 1 in toluene
Sensitive Air Sensitive
BRN 1523669
InChIKeyHVVNJUAVDAZWCB-RXMQYKEDSA-N
CAS DataBase Reference68832-13-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-24/25-26/36
RIDADR NA 1993 / PGIII
WGK Germany 3
F 3-10-23
Hazard Note Irritant/Air Sensitive
HazardClass IRRITANT
HS Code 29339900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
D(-)Prolinol Usage And Synthesis
Chemical PropertiesColorless to light yellow liqui
Uses(2R)-2-Pyrrolidinemethanol is used in the synthesis of potent selective 5-HT7 antagonists.
DefinitionChEBI: The D-enantiomer of prolinol. Metabolite observed in cancer metabolism.
D(-)Prolinol Preparation Products And Raw materials
Preparation Products(R)-(-)-1-(2-Pyrrolidinylmethyl)pyrrolidine-->(R)-2-(Aminomethyl)-1-N-Boc-pyyrolidine-->2-HYDROXYMETHYL-PYRROLIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER-->Pyrrolidine, 2-[(1,1-dimethylethoxy)methyl]-, (R)- (9CI)-->(R)-(+)-1-AMINO-2-(METHOXYMETHYL)PYRROLIDINE
Povidone iodine D(-)Prolinol L-Prolinol-OMe,O-Methyl-L-prolinol, SMP N-Methyl-2-pyrrolidone Ketorolac tromethamine D-Proline BOC-D-PRO-OSU N-Vinyl-2-pyrrolidone Polyvinylpyrrolidone Dexketoprofen trometamol cis-4-Hydroxy-D-proline Ethyl D-(-)-pyroglutamate METHYL-2-PYRROLIDONE PHYTOSPHINGOSINE TRISTEARIN Fosfomycin tromethamine Fmoc-D-proline Pyrrolidine
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