2,5-DIMETHOXYBENZYL ALCOHOL

2,5-DIMETHOXYBENZYL ALCOHOL Basic information
Product Name:2,5-DIMETHOXYBENZYL ALCOHOL
Synonyms:RARECHEM AL BD 0533;2,5-DIMETHOXYBENZYL ALCOHOL;AURORA KA-7072;(2,5-Dimethoxyphenyl)methanol;Benzenemethanol, 2,5-dimethoxy-;2,5-DIMETHOXYBENZYL ALCOHOL 99%;2,5-Dimethoxy-1-(hydroxymethyl)benzene;2,5-Dimethoxybenzenemethanol
CAS:33524-31-1
MF:C9H12O3
MW:168.19
EINECS:251-562-0
Product Categories:Benzhydrols, Benzyl & Special Alcohols;Alcohols;C9 to C30;Oxygen Compounds
Mol File:33524-31-1.mol
2,5-DIMETHOXYBENZYL ALCOHOL Structure
2,5-DIMETHOXYBENZYL ALCOHOL Chemical Properties
Melting point 45-48 °C
Boiling point 122-125 °C1 mm Hg(lit.)
density 1.173 g/mL at 25 °C(lit.)
refractive index n20/D 1.547(lit.)
Fp >230 °F
storage temp. 2-8°C
solubility Chloroform, Methanol
pka14.16±0.10(Predicted)
form Viscous Liquid
color Clear colorless to light yellow
BRN 1947607
LogP1.019 (est)
CAS DataBase Reference33524-31-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 23-24/25-36/37-26
WGK Germany 3
HS Code 29094980
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
2,5-DIMETHOXYBENZYL ALCOHOL Usage And Synthesis
Chemical Propertiesclear colorless to light yellow viscous liquid
Uses2,5-Dimethoxybenzyl Alcohol can be used as a self-indicating standard for the determination of organolithium reagents
Uses2,5-Dimethoxybenzyl alcohol was used as starting reagent in the synthesis of [(S)S]-3,6-dimethoxy-2-(p-tolylsulfinyl)-benzaldehyde. It was used in the synthesis of daunornycinone. It was also used in the preparation of pillar[n]arenes (n = 5 or 6) via cyclooligomerization reaction with an appropriate Lewis acid catalyst.
Synthesis Reference(s)Tetrahedron Letters, 35, p. 6207, 1994 DOI: 10.1016/S0040-4039(00)73392-2
2,5-DIMETHOXYBENZYL ALCOHOL Preparation Products And Raw materials
Raw materialsBenzenemethanol, 2,5-dimethoxy-, 1-acetate-->2,5-dihydroxybenzyl alcohol-->2,5-Dimethoxybenzylbromide-->2,5-Dimethoxybenzaldehyde-->1,4-Dimethoxybenzene
Preparation Products2,5-Dimethoxybenzylamine
Butoxamine hydrochloride METHOXAMINE HYDROCHLORIDE 2,5-BIS-BENZYLOXY-BENZOIC ACID 2,5-DIMETHOXYBENZYL ALCOHOL (2,5-DIMETHOXYPHENYL)(DIPHENYLPHOSPHORYL)METHANOL METHYL 2,5-DIMETHOXYBENZOATE 2,4,5-Trimethoxybenzoic acid pisatin RARECHEM AL BF 0026 3-BROMO-2,5,6-TRIMETHOXYBENZOIC ACID [2-(BENZYLOXY)PHENYL][3-(2,5-DIMETHOXYPHENYL)OXIRAN-2-YL]METHANONE Midodrine hydrochloride 2,5-Bis(2,2,2-trifluoroethoxy)benzoic acid 5-METHOXY-2-(2,2,2-TRIFLUOROETHOXY)BENZOIC ACID 2,4,5-TRIMETHOXYBENZYL ALCOHOL 2,5-DIMETHOXY-3-NITROBENZOIC ACID 2',5'-DIMETHOXYFLAVONE 2,5-Dimethoxybenzoic acid

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