CIS-2-HEXEN-1-OL

CIS-2-HEXEN-1-OL Basic information
Product Name:CIS-2-HEXEN-1-OL
Synonyms:(2Z)-2-Hexen-1-ol;CIS-1-HYDROXY-2-HEXENE;CIS-2-HEXEN-1-OL;FEMA 3924;(z)-2-hexen-1-o;(Z)-2-Hexen-1-ol;(Z)-2-hexenol;(Z)-hex-2-en-1-ol
CAS:928-94-9
MF:C6H12O
MW:100.16
EINECS:213-190-7
Product Categories:Alphabetical Listings;Flavors and Fragrances;Acyclic;Alkenes;Organic Building Blocks;G-H
Mol File:928-94-9.mol
CIS-2-HEXEN-1-OL Structure
CIS-2-HEXEN-1-OL Chemical Properties
Melting point 59.63°C
Boiling point 166 °C(lit.)
density 0.847 g/mL at 25 °C(lit.)
vapor density >1 (vs air)
refractive index n20/D 1.441(lit.)
RTECS MP8395000
FEMA 3924 | (Z)-2-HEXEN-1-OL
Fp 139 °F
storage temp. Flammables area
pka14.45±0.10(Predicted)
form clear liquid
color Colorless to Light yellow to Light orange
Odorat 10.00 % in dipropylene glycol. green cortex leafy green bean nasturtium herbal soapy aldehydic narcissus phenolic
Odor Typegreen
JECFA Number1374
BRN 1719708
Stability:Stable. Flammable. Incompatible with strong oxidizing agents, strong acids.
LogP1.76
CAS DataBase Reference928-94-9(CAS DataBase Reference)
EPA Substance Registry System2-Hexen-1-ol, (2Z)- (928-94-9)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38-36
Safety Statements 16-37/39-36-26
RIDADR UN 1987 3/PG 3
WGK Germany 3
10-23
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29052900
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
CIS-2-HEXEN-1-OL Usage And Synthesis
Chemical Propertiescolourless liquid
Chemical Properties(Z)-2-Hexen-1-ol is used for a green aroma in fragrances and provides a fresher odor than trans-2-hexenol
OccurrenceReported found in fresh and cooked apple, sour cherry, blueberry, blackcurrant, papaya, peach, French fried potato, tomato, butter, hop oil, cognac, red and white wines, black tea.
Usescis-2-Hexen-1-ol is used in the invention of a repellent for Oryzaephilus surinamensis.
Aroma threshold valuesAroma characteristics at 1.0%: impacting fresh vegetative, slightly fatty with a green bean note, witch hazel and fusel alcoholic with a whiskey nuance.
Taste threshold valuesTaste characteristics at 5 to 50 ppm: green vegetative and herbal, raw green beans, tomato and potato with a fusel winey nuance.
General Descriptioncis-2-Hexen-1-ol is a green leaf volatile (GLV) that is commonly found in herbaceous plants and angiosperm trees. In combination with other GLVs, cis-2-hexen-1-ol may disrupt the response of conifer-infesting ambrosia beetle to the host pheromone and kairomones. This ability makes it a promising candidate for the development of log protectants against ambrosia beetles.
Biochem/physiol ActionsOdor at 1%
STRYCHNINE 10,11-Dimethoxystrychnine (-)-CARVYL PROPIONATE 3,5,5-TRIMETHYL-2-CYCLOHEXEN-1-OL L-CARVYL ACETATE 3-METHYL-2-CYCLOHEXEN-1-OL 2-CYCLOHEXEN-1-OL DL-SOBREROL 1-ACETOXY-8-HYDROXY-1,4,4A,9A-TETRAHYDROANTHRAQUINONE Erythorbic Acid RUBRATOXIN B Ascorbyl Palmitate 5-(1-HYDROXY-2,6,6-TRIMETHYL-4-OXOCYCLOHEX-2-ENYL)-3-METHYLPENTA-2,4-DIENOIC ACID 3-METHOXYCYCLOHEXENE TRANS-1,4-CYCLOHEXENEDIOL cis-VERBENOL BRUCINE SULFATE Oxytetracycline dihydrate

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