Fluorotributyltin

Fluorotributyltin Basic information
Product Name:Fluorotributyltin
Synonyms:Fluorotributylstannane;FLUOROTRI-N-BUTYLTIN;TRIBUTYLTIN FLUORIDE;TRIBUTYLTIN FLUORIDE, POLYMER;TRI-N-BUTYLFLUOROTIN;TRI-N-BUTYLTIN FLUORIDE;tributylfluorotin polymer;STANNANE,FLUOROTRIBUTYL-
CAS:1983-10-4
MF:C12H27FSn
MW:309.05
EINECS:217-847-9
Product Categories:Organometallics;Alkyl Metals;Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Sn (Tin) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds
Mol File:1983-10-4.mol
Fluorotributyltin Structure
Fluorotributyltin Chemical Properties
Melting point 269-271 °C(lit.)
Boiling point 285°C (rough estimate)
density 1,28 g/cm3
Fp >150°C
Specific Gravity1.28
Water Solubility Soluble in nonpolar organic solvents. Insoluble in water.
Sensitive Moisture Sensitive
Exposure limitsACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference1983-10-4(CAS DataBase Reference)
EPA Substance Registry SystemTributyltin fluoride (1983-10-4)
Safety Information
Hazard Codes T,N
Risk Statements 21-25-36/38-48/23/25-50/53
Safety Statements 35-36/37/39-45-60-61
RIDADR UN 3261 8/PG 2
WGK Germany 3
RTECS WH8275000
21
TSCA Yes
HazardClass 6.1
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Fluorotributyltin Usage And Synthesis
UsesTri-n-butyltin fluoride is a reagent used for the selective desilylation of bis(silyl) enol ethers. It is also used as antifoulant for marine paints; reagent.
General DescriptionA liquid.
Reactivity ProfileFluorotributyltin is in the family of tin compounds widely used as stabilizers for plastics, additives to paint(as antifouling agents). Some have catalytic properties. Examples include butyl tin, dibutyl tin oxide. Their main hazard is associated with their high toxicity, in skin adsorption or inhalation. Fluorotributyltin is incompatible with strong oxidizers like: ammonium nitrate, barium nitrate, barium chlorate, etc.
Safety ProfilePoison by ingestion. Many tributyl tin compounds are hghly toxic to marine life. Mutation data reported.When heated to decomposition it emits toxic fumes of F-. See also TIN COMPOUNDS and FLUORIDES.
Ammonium hydrogen difluoride Potassium nonafluoro-1-butanesulfonate Fluorotributyltin Dibutyltin oxide Monobutyltin oxide Boron trifluoride sodium fluoride Potassium fluoride TRIMETHYLTIN FLUORIDE TRIPROPYLTIN Aluminum fluoride Dibutyltin dilaurate Sulfur hexafluoride Butylmercaptooxo-stannane FLUORIDE STANDARD Hydrogen fluoride Tetrabutylammonium fluoride Sodium fluoride

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