Phenylsilane

Phenylsilane Basic information

Product Name:	Phenylsilane
Synonyms:	Phenylsilane, 98% 5ML;Phenylsilane,98%;Phenylsilane≥ 98% (GC);PHENYLSILANE;Benzene, silyl-;Fenylsilan;phenyl-silan;Phenylsilane, silyl-
CAS:	694-53-1
MF:	C6H8Si
MW:	108.21
EINECS:	211-772-5
Product Categories:	Silane compounds;Reduction;Si (Classes of Silicon Compounds);Si-H Compounds;Synthetic Organic Chemistry;Organometallic Reagents;Organosilicon;Others
Mol File:	694-53-1.mol

Phenylsilane Chemical Properties

Melting point	-64 to -68°C
Boiling point	120 °C (lit.)
density	0.877 g/mL at 25 °C (lit.)
refractive index	n20/D 1.510(lit.)
Fp	45 °F
storage temp.	Flammables area
form	clear liquid
color	Colorless to Almost colorless
Specific Gravity	0.868
Water Solubility	Contact with water releases a flammable alcohol. Soluble in water (Contact with water releases flammable gases), and most common organic solvents.
Sensitive	Air & Moisture Sensitive
Hydrolytic Sensitivity	7: reacts slowly with moisture/water
BRN	2935169
InChIKey	PARWUHTVGZSQPD-UHFFFAOYSA-N
CAS DataBase Reference	694-53-1(CAS DataBase Reference)
EPA Substance Registry System	Silane, phenyl- (694-53-1)

Safety Information

Hazard Codes	F,Xn
Risk Statements	11-14/15-20/22-36/37/38
Safety Statements	16-43
RIDADR	UN 3399 4.3/PG 2
WGK Germany	1
RTECS	VV4825000
F	10-21
TSCA	Yes
HazardClass	4.3
PackingGroup	II
HS Code	29319090

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

Phenylsilane Usage And Synthesis

Chemical Properties	clear colorless liquid
Uses	Phenylsilane (PhSiH₃) may be used as a reducing agent for the partial reduction of phosphine oxide groups in poly(4,4′-diphenylphenylphosphine oxide) (PAPO) to phosphine. It can also undergo photopolymerization with methyl methacrylate(MMA) to form poly(MMA) containing SiH groups. PhSiH₃ may be used as a silicon source to synthesize crystalline Si nanowires via Au-nanocrystal-seeded supercritical fluid-liquid-solid (SFLS) synthesis.
Uses	phenylsilane is used as a pharmaceutical intermediate.
Definition	ChEBI: Phenylsilane is an organosilicon compound that is benzene in which a hydrogen is replaced by a silyl group. It has a role as a reducing agent. It is an organosilicon compound and a member of benzenes.
Application	Employed in the reduction of esters to ethers. Reduces α,β-unsaturated ketones to saturated ketones in the presence of tri-n-butyltin hydride. Reduces tin amides to tin hydrides. Used in the tin-catalyzed reduction of nitroalkanes to alkanes. Reduces α-halo ketones in presence of Mo(0).

Phenylsilane Preparation Products And Raw materials

Raw materials	Diethyl ether-->Sulfuric acid-->Tetrahydrofuran-->Sodium-->Potassium carbonate-->Lithium Aluminum Hydride-->Magnesium-->Bromobenzene-->Tetrachlorosilane-->Phenyltrichlorosilane-->CHLOROPHENYLSILANE 97
Preparation Products	Diphenylsilane-->1,1,3-trichloropropane-->PHENYLDICHLOROSILANE-->TRIPHENYLETHOXYSILANE

T-BUTYLDIPHENYLMETHOXYSILANE (R)-Methylfluoro(1-naphtyl)phenylsilane Methoxy(methyl)phenylsilane Methyl(hydroxy)phenylsilane Dimethoxymethylphenylsilane Dichloro(ethoxy)phenylsilane Chlorodi(ethoxy)phenylsilane rel-Ethyl(2-methoxyphenyl)[[(1S*)-5α*-methyl-2β*-(1-methylethyl)cyclohexane-1α*-yl]oxy]phenylsilane Ethylmethyl[[5-methyl-2-(1-methylethyl)cyclohexyl]oxy]phenylsilane Butoxy(methyl)phenylsilane DIMETHYL(PENTAFLUOROPHENYL)SILANE METHYL-BIS[2-(7-OXABICYCLO[4.1.0]HEPT-3-YL)ETHYL]PHENYLSILANE Methyl(2-methylphenyl)phenylsilane,Methyl(o-tolyl)phenylsilane Tris(dimethylsiloxy)phenylsilane,TRIS(DIMETHYLSILYLOXY)PHENYLSILANE,TRIS(DIMETHYLSILYLOXY)PHENYLSILANE 96% Chlorodimethylpentafluorophenylsilane Chloro(ethyl)phenylsilane dichloro(1,1-dimethylethyl)phenylsilane,tert-Butyl(dichloro)phenylsilane TRIS(GLYCIDOXYPROPYLDIMETHYLSILOXY)PHENYLSILANE

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