1-AMINO-2-METHYLANTHRAQUINONE

1-AMINO-2-METHYLANTHRAQUINONE Basic information
Product Name:1-AMINO-2-METHYLANTHRAQUINONE
Synonyms:1-AMINO-2-METHYLANTHRAQUINONE;LABOTEST-BB LT00159721;CI 60700;DISPERSE ORANGE 11;TIMTEC-BB SBB003232;1-amino-2-methyl-10-anthracenedione;1-amino-2-methyl-9,10-anthracenedione;1-amino-2-methyl-9,10-anthraquinone
CAS:82-28-0
MF:C15H11NO2
MW:237.25
EINECS:201-408-3
Product Categories:Aminoanthraquinones;Anthraquinones;Intermediates of Dyes and Pigments
Mol File:82-28-0.mol
1-AMINO-2-METHYLANTHRAQUINONE Structure
1-AMINO-2-METHYLANTHRAQUINONE Chemical Properties
Melting point 204-206 °C(lit.)
Boiling point 379.79°C (rough estimate)
density 1.1469 (rough estimate)
refractive index 1.5500 (estimate)
storage temp. Sealed in dry,Room Temperature
form neat
pka-0.53±0.20(Predicted)
Colour Index 60700
color Orange to Amber to Dark red
Water Solubility 332.2ug/L(25 ºC)
Stability:Stable. Incompatible with strong oxidizing agents, mineral acids.
CAS DataBase Reference82-28-0(CAS DataBase Reference)
IARC3 (Vol. 27, Sup 7) 1987
EPA Substance Registry System1-Amino-2-methylanthraquinone (82-28-0)
Safety Information
WGK Germany 3
RTECS CB5740000
10-21
HS Code 2922.39.4500
HazardClass IRRITANT
Hazardous Substances Data82-28-0(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
1-AMINO-2-METHYLANTHRAQUINONE Usage And Synthesis
Chemical Propertiesred powder
Chemical Properties1-Amino-2-methylanthraquinone is a red crystalline substance or powder.
Uses1-Amino-2-methylanthraquinone was used almost exclusively as a dyeand as an intermediate in the production of dyes. It was used as a dyefor synthetic fibers, furs, and thermoplastic resins. The only dyes derived from 1-amino-2-methylanthraquinone that were produced in the United States were C.I. acid blue 47, last produced in 1973, and C.I. solvent blue 13, last produced in 1974 (IARC 1982, HSDB 2009).
UsesDisperse Orange 11 is a dye used in imaging studies including confocal transmission imaging microscopy or polymers. Dyes and metabolites, Environmental Testing
DefinitionChEBI: 1-Amino-2-methylanthraquinone is an anthraquinone.
Preparation2-Methylanthracene-9,10-dione nitrification, then use the method reduction
General DescriptionRed powder.
Air & Water ReactionsInsoluble in water.
Reactivity Profile1-AMINO-2-METHYLANTHRAQUINONE is incompatible with strong oxidizing agents. Forms salts with mineral acids .
Fire HazardFlash point data for 1-AMINO-2-METHYLANTHRAQUINONE are not available; however, 1-AMINO-2-METHYLANTHRAQUINONE is probably combustible.
Safety ProfileConfirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx,.
Potential Exposure1-Amino-2-methylanthraquinone is used almost exclusively as a dye intermediate for the production of a variety of anthraquinone dyes. May be used as a dye for a variety of synthetic fibers, especially acetates, as well as wool, sheepskins, furs, and surface dyeing of thermoplastics. None of the dyes that can be prepared from it are presently produced in commercial quantities.1Amino-2-methylanthraquinone had been produced commercially in the United States since 1948, but production was last reported by a single company in 1970. The potential for exposure is greatest among workers engaged in the dyeing of textiles. 1-Amino-2-methylanthraquinone is not presently used in consumer products according to the CPSC.
Carcinogenicity1-Amino-2-methylanthraquinone is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
ShippingUN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required
Properties and Applicationsred light orange
1-AMINO-2-METHYLANTHRAQUINONE Preparation Products And Raw materials
Raw materials2-methyl-1-nitroanthraquinone-->Dimethylamine-->Piperidine-->Dibutylamine-->2,3-Dichloro-1,4-naphthoquinone-->2-Methyl anthraquinone-->2-Methyl anthraquinone
Preparation Products1-Hydroxy anthraquinone
1-amino-9,10-dioxo-9,10-dihydroanthracene-2-carbaldehyde 1-Amino-4-methylamino-9,10-dioxo-9,10-dihydroanthracene-2-carboxylicacidmethylester dynemicin A 1-AMINO-2-METHYLANTHRAQUINONE anthra[1,2-c]benzimidazo[2,1-i]benzo[lmn][2,8]phenanthroline-5,9,20(6H)-trione 1,4-DIAMINO-2,3-DICYANO-9,10-ANTHRAQUINONE dynemicin P RARECHEM AL BW 0630 Disperse Blue 60 1-AMINO-4-BROMO-2-METHYLANTHRAQUINONE 1-amino-4-chloro-2-methylanthraquinone N-BENZOYL-N'-(2-METHYL-9,10-DIOXO-9,10-DIHYDRO-1-ANTHRACENYL)THIOUREA SOLWAY BLUE RN 1-AMINO-2-HYDROXYMETHYLANTRAQUINONE RARECHEM AL BO 0603 Vat Violet 13 2-methyl-1-nitroanthraquinone Vat Red 10

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