2-CHLOROPHENYLZINC IODIDE

2-CHLOROPHENYLZINC IODIDE Basic information
Product Name:2-CHLOROPHENYLZINC IODIDE
Synonyms:2-CHLOROPHENYLZINC IODIDE;2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;2-chlorophenylzinc iodide solution;2-Chlorophenylzinc iodide solution 0.5 in THF;2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles;2-Chlorophenylzinc iodide solution 0.5M in THF;2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran;2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
CAS:148651-35-8
MF:C6H4ClIZn
MW:303.84
EINECS:
Product Categories:Aryl;Organozinc Halides;Reike and Organozinc Reagents
Mol File:148651-35-8.mol
2-CHLOROPHENYLZINC IODIDE Structure
2-CHLOROPHENYLZINC IODIDE Chemical Properties
density 0.973 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
Sensitive Air & Light Sensitive
Exposure limitsACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
CAS DataBase Reference148651-35-8
Safety Information
Hazard Codes F,Xn
Risk Statements 11-19-22-36/37/38-40-36/37
Safety Statements 16-26-33-36-36/37
RIDADR UN 2056 3/PG 2
WGK Germany 1
HazardClass 4.3
MSDS Information
ProviderLanguage
SigmaAldrich English
2-CHLOROPHENYLZINC IODIDE Usage And Synthesis
Uses2-Chlorophenylzinc iodide is an organozinc compound, which can be used as a reactant in Negishi cross-coupling reaction to construct carbon-carbon bonds by reacting with organic halides using nickel or palladium catalysts.
It can also be utilized as a reactant to prepare:
  • Arylmethanes via rhodium-catalyzed cross-coupling reaction with methyl halides.
  • (2-chlorobenzyl)trimethylsilane by Rh-catalyzed cross-coupling reaction with (iodomethyl)trimethylsilane.
  • Dichloro biphenyl by palladium catalyzed oxidative homocoupling reaction using N-chlorosuccinimide (NCS) or O2 as the oxidant.

2-CHLOROPHENYLZINC IODIDE Preparation Products And Raw materials
Preparation Products2,2'-DICHLOROBIPHENYL
6-ETHOXY-6-OXOHEXYLZINC BROMIDE 5-ETHOXY-5-OXOPENTYLZINC BROMIDE (1,3-DIOXAN-2-YLETHYL)ZINC BROMIDE 1-METHYLBUTYLZINC BROMIDE PHENYLZINC BROMIDE 1-METHYLHEXYLZINC BROMIDE 4-CHLOROBUTYLZINC BROMIDE (1,3-DIOXOLAN-2-YLETHYL)ZINC BROMIDE CYCLOPROPYLZINC BROMIDE SOLUTION 0.5M I& 1-HEXYLZINC BROMIDE 5-(1,3-DIOXOLAN-2-YL)-2-THIENYLZINC BROMIDE 4-ETHOXY-4-OXOBUTYLZINC BROMIDE 2,5-DICHLOROPHENYLZINC IODIDE 2-CHLOROPHENYLZINC IODIDE 2-CHLORO-6-METHYLPHENYLZINC IODIDE 2-CHLORO-4-FLUOROPHENYLZINC IODIDE 2,4-DICHLOROPHENYLZINC IODIDE 2,3-DICHLOROPHENYLZINC IODIDE

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