SODIUM TRIMETHYLSILANOLATE

SODIUM TRIMETHYLSILANOLATE Basic information
Product Name:SODIUM TRIMETHYLSILANOLATE
Synonyms:SodiuM odiuM triMethylsilanolate;SodiuM triMethylsilanolate 95%;SodiuM triMethylsilanolate, 1.0 M solution in THF, HySeal Spc;SodiuM triMethylsilanolate, 1.0 M solution in THF, J&KSeal;SODIUM TRIMETHYLSILANOLATE;TRIMETHYLSILANOL, SODIUM SALT;trimethyl-silanosodiumsalt;SODIUM TRIMETHYLSILANOLATE, 1.0M SOLUTIO N IN DICHLOROMETHANE
CAS:18027-10-6
MF:C3H9NaOSi
MW:112.18
EINECS:241-939-8
Product Categories:Chemical Synthesis;Organic Bases;Synthetic Reagents
Mol File:18027-10-6.mol
SODIUM TRIMETHYLSILANOLATE Structure
SODIUM TRIMETHYLSILANOLATE Chemical Properties
Melting point 230 °C (dec.)(lit.)
density 1.283 g/mL at 25 °C
Fp −2 °F
solubility DMSO (Sparingly)
form Solid
color White to Off-White
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
BRN 3912148
InChIKeyHSNUIYJWTSJUMS-UHFFFAOYSA-N
CAS DataBase Reference18027-10-6
EPA Substance Registry SystemSilanol, trimethyl-, sodium salt (18027-10-6)
Safety Information
Hazard Codes T,C,F
Risk Statements 34-40-23/24/25-20/21/22-19-11-37
Safety Statements 26-36/37/39-45-28-27-16
RIDADR UN 3267 8/PG 2
WGK Germany 3
3-10-21
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
SODIUM TRIMETHYLSILANOLATE Usage And Synthesis
Purification MethodsIt is very soluble in Et2O and *C6H6 but moderately soluble in pet ether. It is purified by sublimation at 130-150o in a high vacuum. [Hyde et al. J Am Chem Soc 75 5615 1953, Tatlock & Rochow J Org Chem 17 1555 1952, Beilstein 4 III 1856.]
SODIUM TRIMETHYLSILANOLATE Preparation Products And Raw materials
Preparation ProductsSODIUM P-CHLOROBENZOATE-->3-CHLOROPROPYLTRIS(TRIMETHYLSILOXY)SILANE-->Phenyltris(trimethylsiloxy)silane-->TETRAFLUORO-2-(PENTAFLUOROETHOXY)ETHANESULFONIC ACID SODIUM SALT
Cupric tartrate ETHYLALUMINUM SESQUICHLORIDE PHENYLMAGNESIUM BROMIDE Butylmagnesium chloride Potassium tert-butoxide Tributylphosphine 4-tert-Butylphenylboronic acid Trimethylphosphine Lithium bis(trimethylsilyl)amide trimethylsilylethynylmagnesium bromide Trimethylaluminium PHENYL(DIMETHYL)SILANOLATE SODIUM SALT SODIUM TRIMETHYLSILANOLATE Dimethylphenylsilanol sodium salt, 97% SODIUM (THIEN-2-YL)DIMETHYLSILANOLATE SODIUM (N-(BOC)-2-INDOLYL)DIMETHYLSILANOLATE SODIUM DIMETHYL(4-METHOXYPHENYL)SILANOLATE DIMETHYL-2-FURYLSILANOL SODIUM SALT

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