1,3,4,6-Tetra-O-acetyl-β-D-mannopyranose

1,3,4,6-Tetra-O-acetyl-β-D-mannopyranose Basic information
Product Name:1,3,4,6-Tetra-O-acetyl-β-D-mannopyranose
Synonyms:1,3,4,6-TETRA-O-ACETYL-BETA-D-MANNOPYRANOSE;1,2,3,4-TETRA-O-ACETYL-BETA-D-MANNOPYRANOSE;1,3,4,6-Tetraacetate β-D-Mannopyranose;1,3,4,6-O-Tetraacetyl-β-D-Mannopyranose;[(2R,3R,4R,5S,6S)-3,4,6-triacetyloxy-5-hydroxyoxan-2-yl]methyl acetate;(2S,3S,4R,5R,6R)-6-(Acetoxymethyl)-3-hydroxytetrahydro-2H-pyran-2,4,5-triyl triacetate;1,3,4,6-Tetra-O-acetyl-β;1,3,4,6-Tetra-O-acetyl-?D-mannopyranose
CAS:18968-05-3
MF:C14H20O10
MW:348.3
EINECS:
Product Categories:Intermediates & Fine Chemicals;Labeling and Diagnostics Reagents;Biochemistry;O-Substituted Sugars;Carbohydrates & Derivatives;Pharmaceuticals;chiral;Sugars;Glycon Biochem
Mol File:18968-05-3.mol
1,3,4,6-Tetra-O-acetyl-β-D-mannopyranose Structure
1,3,4,6-Tetra-O-acetyl-β-D-mannopyranose Chemical Properties
Melting point 160-161 °C(lit.)
Boiling point 425.5±45.0 °C(Predicted)
density 1.33±0.1 g/cm3(Predicted)
refractive index -22.5 ° (C=1.4, CHCl3)
storage temp. Sealed in dry,2-8°C
solubility very faint turbidity in Chloroform
form powder to crystal
pka12.22±0.70(Predicted)
color White to Almost white
optical activity[α]19/D 68°, c = 0.7 in pyridine
BRN 96634
InChIKeySHBHJRVMGYVXKK-XVIXHAIJSA-N
CAS DataBase Reference18968-05-3(CAS DataBase Reference)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 29400090
MSDS Information
ProviderLanguage
SigmaAldrich English
1,3,4,6-Tetra-O-acetyl-β-D-mannopyranose Usage And Synthesis
Uses1,3,4,6-Tetra-o-acetyl-beta-d-mannopyranose is an intermediate in the preparation of precursors of 2-[18F]fluoro-2-deoxy-D-glucose for diagnostic use in positron emission tomography.
1,3,4,6-Tetra-O-acetyl-β-D-mannopyranose Preparation Products And Raw materials
Raw materials1 2-O-(1-ETHOXYETHYLIDENE)-BETA-D-MANNO&
D-Mannose D-LYXOSE 1,3,4,6-Tetra-O-acetyl-β-D-mannopyranose L(+)-Rhamnose monohydrate 1,2,3,4-TETRAMETHOXYBUTANE Butane, 1,1,3-triethoxy- 1,3,4,6-Tetra-O-acetyl-2-deoxy-D-glucopyranose Mannitol 1,2,3,4,6-PENTA-O-BENZOYL-BETA-D-MANNOPYRANOSE 1-5-ANHYDRO-D-MANNITOL CRYSTALLINE BETA-METHYL-D-LYXOPYRANOSIDE Diacetin 2-[(Acetyloxy)methoxy]ethyl acetate D-Mannitol 1,4-DIACETOXYBUTANE 1,3-Diacetoxy-2-(acetoxymethoxy)propane (R)-1,2-4-TRIACETOXYBUTANE 1,1,3-TRIETHOXYPROPANE

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