2-Allylcyclohexanone

2-Allylcyclohexanone Basic information

Product Name:	2-Allylcyclohexanone
Synonyms:	2-ALLYLCYCLOHEXANONE;2-(2-PROPENYL)CYCLOHEXANONE;TIMTEC-BB SBB006544;O-ALLYLCYCLOHEXANONE;2-(2-propenyl)-cyclohexanon;Cyclohexanone, 2-allyl-;2-allylcyclohexan-1-one;2-Allylcyclohexanone, 97% 1GR
CAS:	94-66-6
MF:	C9H14O
MW:	138.21
EINECS:	202-352-2
Product Categories:	C9;Carbonyl Compounds;Ketones
Mol File:	94-66-6.mol

2-Allylcyclohexanone Chemical Properties

Boiling point	94 °C/23 mmHg (lit.)
density	0.927 g/mL at 25 °C (lit.)
refractive index	n20/D 1.469(lit.)
Fp	>230 °F
form	clear liquid
color	Colorless to Light yellow to Light orange
Specific Gravity	0.927
Water Solubility	Insoluble
CAS DataBase Reference	94-66-6(CAS DataBase Reference)
NIST Chemistry Reference	Cyclohexanone, 2-(2-propenyl)-(94-66-6)
EPA Substance Registry System	Cyclohexanone, 2-(2-propenyl)- (94-66-6)

Safety Information

Hazard Codes	Xn,Xi
Risk Statements	20/21/22-36/37/38
Safety Statements	22-26-36/37/39-45-37/39
RIDADR	UN 3077
WGK Germany	3
HS Code	29142990

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

2-Allylcyclohexanone Usage And Synthesis

Chemical Properties	clear light yellow liquid
Uses	2-Allylcyclohexanone may be used in the synthesis of the following: bicyclo[3.3.1]non-2-en-9-one R-(-)-epilachnene, an antipode of the defensive droplets from the Mexican bean beetle, Epilachna varivestis
Synthesis Reference(s)	Chemistry Letters, 13, p. 1721, 1984 Journal of the American Chemical Society, 85, p. 207, 1963 DOI: 10.1021/ja00885a021 The Journal of Organic Chemistry, 51, p. 421, 1986 DOI: 10.1021/jo00354a001
General Description	2-Allylcyclohexanone is a β,γ-unsaturated ketone. Selective oxidation of 2-allylcyclohexanone by benzonitrile-hydrogen peroxide has been reported. Asymmetric synthesis of 2-alkylcyclohexanones by alkylation of cyclohexanone enamines (III) of L-proline ester derivatives has been described. Oxidation of 2-allylcyclohexanone by 90% hydrogen peroxide catalyzed by arsonated polystyrene has been studied.

2-Allylcyclohexanone Preparation Products And Raw materials

Raw materials

Potassium hydroxide-->Benzotrifluoride-->3-propan-2-yloxyprop-1-ene-->Carbonic acid, 1-cyclohexen-1-yl 2-propen-1-yl ester-->Stannane, tributyl(1-cyclohexen-1-yloxy)--->Cyclohexane, (2-propen-1-yloxy)--->ALLYL N-PROPYL ETHER-->Allyl 2-Oxocyclohexanecarboxylate-->N-(1-Cyclohexen-1-yl)morpholine-->1-Pyrrolidino-1-cyclohexene-->Allyl Benzyl Ether-->ALLYL ETHYL ETHER-->ALLYL METHYL ETHER-->Allyl acetate-->Allyl phenyl ether-->Allyl bromide

2-Allylcyclohexanone Adrenosterone CYCLOPENTADIENE-QUINONE (2:1)ADDUCT Allylthiourea Allyl glycidyl ether 4,4,10-TRIMETHYL TRICYCLO[7,3,1,0(1-6)]-6,10-TRIDECADIENE-2,8-DIONE 2ALPHA-METHYLCORTISONE Meprednisone 2-Methylcyclohexanone Sodium allylsulfonate CORTISONE 21-DEOXYCORTISONE CUCURBITACIN I Prednisone Allylamine Cyclohexanone METHYLCYCLOHEXANONE Cortisone acetate

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