ChemicalBook Product Catalog Biochemical Engineering Amino Acids and Derivatives Glycine derivative Boc-D-Phenylglycine

Boc-D-Phenylglycine

Boc-D-Phenylglycine Basic information
Product Name:Boc-D-Phenylglycine
Synonyms:Boc-(R)-2-aminobenzeneacetic acid;N-(tert-Butoxycarbonyl)-D-2-phenylglycine;N-Boc-D-2-phenylglycine;N-(tert-butoxycarbonyl)-D-alpha-phenylglycine;N-Boc-D-2-phenylglycine Boc-D-Phg-OH;(R)-2-((tert-butoxycarbonyl)aMino)-2-phenylacetic acid;N-Boc-D-phenylglycine (Boc-D-Phg-OH);BOC-(PHENYL)GLY-OH
CAS:33125-05-2
MF:C13H17NO4
MW:251.28
EINECS:1533716-785-6
Product Categories:Phenylglycine [Phg];Unusual Amino Acids;Amino Acids;Amino Acids (N-Protected);Biochemistry;Boc-Amino Acids;Boc-Amino acid series
Mol File:33125-05-2.mol
Boc-D-Phenylglycine Structure
Boc-D-Phenylglycine Chemical Properties
Melting point 88-91 °C
alpha -142 º (c=1% in ethanol)
Boiling point 407.2±38.0 °C(Predicted)
density 1.182±0.06 g/cm3(Predicted)
refractive index -140 ° (C=1, EtOH)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO, Methanol
pka3.51±0.10(Predicted)
form Crystalline Powder
color White
optical activity[α]20/D 141.0±5.0°, c = 1% in ethanol
Water Solubility Insoluble in water. Slightly soluble in DMSO and methanol.
BRN 3033982
CAS DataBase Reference33125-05-2(CAS DataBase Reference)
Safety Information
Safety Statements 24/25
WGK Germany 3
HazardClass IRRITANT
HS Code 29242990
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Boc-D-Phenylglycine Usage And Synthesis
Chemical PropertiesWhite powder
UsesIt is a reagent of choice for assignment of absolute configuration of chiral primary amines by 1H NMR, giving better results than Mosher's acid ((R)-(+)-?-Methoxy-?-(trifluoromethyl)-phenyl-acetic acid. αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.
Boc-D-Phenylglycine Preparation Products And Raw materials
Boc-Aib-OH Boc-D-Phenylglycine L-Phenylglycine BOC-DL-Phg-OH N-Carbobenzyloxyglycine N-BOC-DL-PHENYLGLYCINE Glycine BOC-GLY-LEU-OH 4-Aminophenylacetic acid Phenoxybenzamine hydrochloride BOC-Glycine Anilinoacetic acid 4-Hydroxy-D-(-)-2-phenylglycine BOC-PHG-OSU, N- BOC-L-PHENYLGLYCINE N-HYDROXYSUCCINMIDE ESTER 5-PHENYL-TRYPTOPHAN[TRP(5-PH)] (S)-FMOC-(3-BOC-AMINOMETHYL)-PHENYLGLYCINE D-2-Phenylglycine Tamoxifen 2-Phenoxyethanol
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