Vinyltrimethoxysilane

Vinyltrimethoxysilane Basic information
Description
Product Name:Vinyltrimethoxysilane
Synonyms:(TRIMETHOXYSILYL)ETHYLENE;VINYLTRIMETHOXYSILANE;ETHENYLTRIMETHOXYSILAN;DOW CORNING(R) PRODUCT Q9-6300;(trimethoxysilyl)ethene;trimethoxyvinyl-silan;Union Carbide A-171;v4917
CAS:2768-02-7
MF:C5H12O3Si
MW:148.23
EINECS:220-449-8
Product Categories:Functional Materials;Si (Classes of Silicon Compounds);Silane Coupling Agents;Si-O Compounds;Trialkoxysilanes;Vinyl Silanes (Silane Coupling Agents);Vinylsilanes, Allylsilanes;Adhesion Promoters;Coupling Agents;Surface Modifiers;Silicone series;silane;2768-02-7
Mol File:2768-02-7.mol
Vinyltrimethoxysilane Structure
Vinyltrimethoxysilane Chemical Properties
Melting point <-70°C
Boiling point 123 °C (lit.)
density 0.968 g/mL at 25 °C (lit.)
vapor pressure 88 hPa (55 °C)
refractive index n20/D 1.392(lit.)
Fp 73 °F
storage temp. Store below +30°C.
form liquid
Specific Gravity0.970
color Colorless to Almost colorless
explosive limit1.1%(V)
Water Solubility slightly soluble
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 1099136
InChIKeyNKSJNEHGWDZZQF-UHFFFAOYSA-N
LogP-2--0.82 at 20℃
CAS DataBase Reference2768-02-7(CAS DataBase Reference)
NIST Chemistry ReferenceVinyltrimethoxysilane(2768-02-7)
EPA Substance Registry SystemVinyltrimethoxysilane (2768-02-7)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38-20
Safety Statements 26-36/37/39-37/39-16
RIDADR UN 1993 3/PG 2
WGK Germany 1
RTECS VV6770000
10-21
Autoignition Temperature235 °C
TSCA Yes
HazardClass 3
PackingGroup III
HS Code 29310095
ToxicityLD50 orally in Rabbit: 7120 mg/kg LD50 dermal Rabbit 3259 mg/kg
MSDS Information
ProviderLanguage
Ethenyltrimethoxysilan English
SigmaAldrich English
ACROS English
ALFA English
Vinyltrimethoxysilane Usage And Synthesis
DescriptionVinyltrimethoxysilane, is used as a polymer modifier via grafting reactions. The resulting pendant trimethoxysilyl groups can function as moisture-activated crosslinking sites. The Silane grafted polymer is processed as a thermoplastic and crosslinking occurs after fabrication of the finished article upon exposure to moisture.

Vinyltrimethoxysilane is mainly applied in these aspects:
  1. In the preparation of moisture-curing polymers, e.g. polyethylene. Silane crosslinked polyethylene is widely used as cable isolation, and sheathing mainly in low voltage applications as well as for hot water/sanitary pipes and underfloor heating.
  2. As a co-monomer for the preparation of different polymers such as polyethylene or acrylics. Those polymers show an improved adhesion to inorganic surfaces and they can also be crosslinked with moisture.
  3. As an efficient adhesion promoter for various mineral-filled polymers, improving mechanical and electrical properties especially after exposure to moisture.
  4. Improving the compatibility of fillers with polymers, leading to a better dispersibility, reduced melt viscosity and easier processing of filled plastics.
  5. Pre-treating of glass, metals, or ceramic surfaces, improve the adhesion of coatings on these surfaces and corrosion resistance.
  6. As moisture scavenger, it reacts rapidly with water. This effect is used widely in sealants.


Chemical PropertiesColorless transparent liquid
UsesVTMS may be used to provide superhydrophobicity to different materials like TiO2, talc, kaolin, magnesium oxide nanoparticles, ammonium phosphate and PEDOT. It modifies the surface by capping the material and creates a protective layer that is water resistant and can be used in major coating industries.
General DescriptionVinyltrimethoxysilane (VTMS) is a silane coupling agent with silicon and hydroxyl groups that can be used to enhance the wettability and improve the superhydrophobic characteristics of different composites.
Flammability and ExplosibilityFlammable
3-methyl-1-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-1,4-dien-3-ol CADMIUM 2,4-PENTANEDIONATE, HYDRATE Vinyl tris(trimethylsiloxy)silane Calcium acetylacetonate Tri(isopropoxy)vinylsilane Bis(2,4-pentanedionato-O,O')palladium(II) Vinyltris(methylethylketoxime)silane VINYL TERMINATED POLYDIMETHYLSILOXANE Sodium ethylenesulphonate OLIGO-VINYLTRIMETHOXYSILANE TRIMETHOXYSILYL MODIFIED POLYETHYLENE Silicon tetrahydride Coupling agent VINYLGLOVES Trimethoxysilylpropanethiol SILANE COUPLING AGENT Vinyltriacetoxysilane Triphenoxyvinylsilane

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