Azocyclotin

Azocyclotin Basic information
Product Name:Azocyclotin
Synonyms:AZOCYCLOTIN PESTANAL (1-(TRICYCLO- HEXYL;AZOCYCLOTIN, 250MG, NEAT;Tricyclotin;1-(tricyclohexylstannyl)-1H-1,2,4-triazole azocyclotin;1H-1,2,4-Triazole, 1-(tricyclohexylstannyl)-;azocyclotin (bsi,iso,esa);AZOCYCLOTIN STANDARD;Clermait
CAS:41083-11-8
MF:C20H35N3Sn
MW:436.22
EINECS:255-209-1
Product Categories:INSECTICIDE;A-BPesticides&Metabolites;AR to AZ;A;AcaricidesAlphabetic;Alpha sort;Pesticides;Pesticides&Metabolites
Mol File:41083-11-8.mol
Azocyclotin Structure
Azocyclotin Chemical Properties
Melting point 210℃
Boiling point 487.4±28.0 °C(Predicted)
vapor pressure 2×10-11 Pa (20 °C, est.)
storage temp. 0-6°C
solubility Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
pka5.36 (weak base)
Water Solubility 0.12 mg l-1 (20 °C)
form neat
BRN 621636
CAS DataBase Reference41083-11-8(CAS DataBase Reference)
NIST Chemistry Reference1H-1,2,4-triazole, 1-(tricyclohexylstannyl)-(41083-11-8)
EPA Substance Registry SystemAzocyclotin (41083-11-8)
Safety Information
Hazard Codes T+;N,N,T+
Risk Statements 25-26-37/38-41-50/53
Safety Statements 26-28-36/37/39-38-45-60-61
RIDADR UN 2786
WGK Germany 3
RTECS WH8637700
HazardClass 6.1(a)
PackingGroup I
Hazardous Substances Data41083-11-8(Hazardous Substances Data)
MSDS Information
Azocyclotin Usage And Synthesis
UsesAzocyclotin is used to control all motile stages of spider mites on fruit, vines, hops, cotton, vegetables and ornamentals.
UsesAzocyclotin is an organotin aracacide used in the control of mites. Azocyclotin showed weak antifeedant activity against other insects such as Spodoptera littoralis.
DefinitionChEBI: A member of the class of triazoles that is 1,2,4-triazole substituted at position 1 by a tricyclohexylstannyl group.
Metabolic pathwayThe sedimentation of particles coated with the pesticide is relatively fast. Shortly after application of 14C-azocyclotin, distribution, solubilizing, and metabolism in fresh water microcosms begin, and azocyclotin is quickly hydrolyzed to cyhexatin (tricyclohexyltin hydroxide) by splitting of the triazole residue, and, according to the solubility of cyhexatin, cyhexatin is mainly absorbed to sediment and the layer of biota in direct contact with the sediment and further undergoes successive metabolism to result in dicyclohexyltin oxide and cyclohexyltin acid.
DegradationAzocyclotin undergoes hydrolysis with DT50 values (22 °C) of 96 hours at pH 4,81 hours at pH 7 and 8 hours at pH 9 (I'M).
Azocyclotin Preparation Products And Raw materials
Raw materialsMagnesium-->Tin-->Chlorocyclohexane-->TRICYCLOHEXYLTIN CHLORIDE-->Cyhexatin
Preparation ProductsAzocyclotin suspensoid-->Azocyclotin W.P.
Abamectin+Azocyclotin,E.C. Cyclohexanecarboxylic acid TRICYCLOHEXYLTIN HYDRIDE Azocyclotin 1,2,4-Triazole AZOCYCLOTIN 100UG/ML IN ACETONITRILE 1ML 1,2,4-TRIAZOLE Azocyclotin E.C. Azocyclotin+Tetradifon,E.C. Azocyclotin suspensoid Cyclohexanemethanol Pyridaben+Azocyclotin,W.P.,Pyridaben+Azocyclotin,E.C.(16%) Cyclohexylbenzene Isocyanatocyclohexane Molasses Azocyclotin W.P. Clofentezine+Azocyclotin,suspension CYHEXATIN/AZOCYCLOTIN

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