2-Aminonaphthalene-1-sulfonic acid

2-Aminonaphthalene-1-sulfonic acid Basic information
Product Name:2-Aminonaphthalene-1-sulfonic acid
Synonyms:SUPER J ACID;2 NAPHTHYLAMINE SULPHONIC ACID;2-NAPHTHYLAMINE-1-SULFONIC ACID;2-AMINO-1-NAPHTHALENESULFONIC ACID;2-AMINONAPHTHALENE-1-SULFONIC ACID;TOBIAS ACID;1-Naphthalenesulfonic acid, 2-amino-;1-Naphthalenesulfonicacid,2-amino-
CAS:81-16-3
MF:C10H9NO3S
MW:223.25
EINECS:201-331-5
Product Categories:Organics;Intermediates;Intermediates of Dyes and Pigments
Mol File:81-16-3.mol
2-Aminonaphthalene-1-sulfonic acid Structure
2-Aminonaphthalene-1-sulfonic acid Chemical Properties
Melting point 180 °C
Boiling point 220°C (rough estimate)
density 1.3588 (rough estimate)
refractive index 1.5250 (estimate)
storage temp. -20°C Freezer, Under inert atmosphere
solubility DMSO (Slightly), Methanol (Slightly, Heated), Water (Slightly, Heated)
pkapK1: 2.35 (25°C)
form Solid
color White to Off-White
Water Solubility 4.083g/L(20 ºC)
Merck 14,6406
BRN 613084
CAS DataBase Reference81-16-3(CAS DataBase Reference)
NIST Chemistry Reference2-Naphthylamine-1-sulfonic acid(81-16-3)
EPA Substance Registry System2-Amino-1-naphthalenesulfonic acid (81-16-3)
Safety Information
Risk Statements 36/37/38-40
Safety Statements 26-36/37/39
RIDADR 2585
WGK Germany 1
RTECS QK1250000
TSCA Yes
HS Code 2921.45.9010
HazardClass 8
PackingGroup III
Hazardous Substances Data81-16-3(Hazardous Substances Data)
MSDS Information
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2-Naphthylamine-1-sulfonic acid English
SigmaAldrich English
ALFA English
2-Aminonaphthalene-1-sulfonic acid Usage And Synthesis
Chemical PropertiesGrey white to light pink powder
UsesAzo dye intermediate, optical brighteners.
Uses2-Amino-1-naphthalenesulfonic acid has been used in the preparation of 2-(2-naphthylamino)benzoxazole by reacting with 2-chlorobenzoxazole.
General Description2-Amino-1-naphthalenesulfonic acid is a manufacturing intermediate in the monosulfo monoazo color additive D&C Red No. 34 and its lakes.
Purification MethodsCrystallise the acid under nitrogen from boiling water and dry it in a steam oven [Bryson Trans Faraday Soc 47 522, 527 1951]. [Beilstein 14 III 2240, 14 IV 2792.]
2-Naphthylamine Sulfanilic acid p-Toluenesulfonic acid Ethyl 2-(Chlorosulfonyl)acetate Taurine 4-Amino-benzenesulfonic acid monosodium salt Ammonium sulfamate SULFONIC ACID Folic acid Glycine 1-DODECANESULFONIC ACID SODIUM SALT Chlorosulfonic acid Sulfamic acid phosphoric acid 1,5-Naphthalenedisulfonic acid 1-Naphthylamine Molasses 1-Naphthalenesulfonic acid

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