PROTHOATE

PROTHOATE Basic information
Product Name:PROTHOATE
Synonyms:Trimethoate;O,O-diethyl isopropylcarbamoylmethyl phosphorodithioate;prothoate (bsi,iso);Prothoate: (Isopropyl diethyldithiophosphorylacetamide);prothoate (ISO) O,O-diethyl isopropylcarbamoylmethyl phosphorodithioate;FAC(pesticide);2-(diethoxythiophosphorylthio)-N-isopropyl-acetamide;2-diethoxyphosphinothioylsulfanyl-N-propan-2-ylacetamide
CAS:2275-18-5
MF:C9H20NO3PS2
MW:285.36
EINECS:218-893-2
Product Categories:
Mol File:2275-18-5.mol
PROTHOATE Structure
PROTHOATE Chemical Properties
Melting point 28.5℃
Boiling point 152-155℃ (0.1-0.2 Torr)
density 1.151 g/cm3(Temp: 32 °C)
refractive index 1.5182 (589.3 nm 20℃)
form solid
pka14.12±0.46(Predicted)
Water Solubility 2.5g/L(20 ºC)
CAS DataBase Reference2275-18-5
EPA Substance Registry SystemProthoate (2275-18-5)
Safety Information
Hazard Codes T+
Risk Statements 27/28-52/53
Safety Statements 28-36/37-45-61
RIDADR 2783
HazardClass 6.1(a)
PackingGroup I
Hazardous Substances Data2275-18-5(Hazardous Substances Data)
MSDS Information
PROTHOATE Usage And Synthesis
Chemical PropertiesWhite, crystalline solid.Soluble in most organic solvents.
Chemical PropertiesProthoate is an amber to yellow crystalline solid with a camphor-like odor.
UsesFungicide, ovicide.
DefinitionChEBI: Prothoate is an organic thiophosphate.
General DescriptionColorless crystalline solid, with a camphor-like odor. Technical product is an amber to yellow semi-solid. Used as an insecticide and an acaricide.
Reactivity ProfileOrganothiophosphates, such as PROTHOATE, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
HazardToxic by ingestion and skin absorption, cholinesterase inhibitor.
Health HazardThis is a highly toxic material capable of causing death or permanent injury due to exposures during normal use. Small doses at frequent intervals are additive. Similar to parathion.
Fire Hazard(Non-Specific -- Organophosphorus Pesticide, n.o.s.) Container may explode in heat of fire. Fire and runoff from fire control water may produce irritating or poisonous gases.
Potential ExposureA potential danger to those involved in the manufacture, formulation and application of the sys- temic acaricide and insecticide.
ShippingUN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
IncompatibilitiesOrganophosphates are susceptible to for- mation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercap- tans, nitrides, and sulfides (releasing heat, toxic and possi- bly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur).
Waste DisposalIn accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed prop- erly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
PROTHOATE Preparation Products And Raw materials
N-(Mercaptoacetyl)leucine ethyl ester S-ester with O,O-diethylphosphor odithioate PROTHOATE PIPEROPHOS O,O-Diethyl Dithiophosphate AMMoniuM Salt O,O-DIMETHYLS-(N-METHYLCARBAMOYLMETHYL)PHOSPHORODITHIOATE

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