Cylopropylmethyl chloride

Cylopropylmethyl chloride Basic information
Product Name:Cylopropylmethyl chloride
Synonyms:CYCLOPROPYLMETHYL CHLORIDE;(CHLOROMETHYL)CYCLOPROPANE;Cyclopropane, (chloromethyl)-;Cyclopropane,(chloromethyl)-;Cylopropylmethylchloride;Cyclopropylmethychloride;Cyclopropylmethyl Chloride, Pract.;1 -(Chloromethyl)cyclopropane
CAS:5911-08-0
MF:C4H7Cl
MW:90.55
EINECS:227-632-1
Product Categories:Cycloalkanes;Alkyl;Halogenated Hydrocarbons;Organic Building Blocks
Mol File:5911-08-0.mol
Cylopropylmethyl chloride Structure
Cylopropylmethyl chloride Chemical Properties
Melting point -91°C
Boiling point 87-89 °C(lit.)
density 0.98 g/mL at 25 °C(lit.)
refractive index n20/D 1.435(lit.)
Fp 29 °F
storage temp. Inert atmosphere,2-8°C
solubility soluble in Chloroform, Methanol
form clear liquid
color Colorless to Almost colorless
Water Solubility Not miscible in water.
BRN 635697
InChIKeyZVTQWXCKQTUVPY-UHFFFAOYSA-N
CAS DataBase Reference5911-08-0(CAS DataBase Reference)
NIST Chemistry Reference(Chloromethyl)cyclopropane(5911-08-0)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36/37/38
Safety Statements 16-26-36/37/39
RIDADR UN 1993 3/PG 2
WGK Germany 3
HazardClass 3
PackingGroup II
HS Code 29035990
MSDS Information
ProviderLanguage
Cylopropylmethyl chloride English
SigmaAldrich English
ALFA English
Cylopropylmethyl chloride Usage And Synthesis
Chemical PropertiesColorless to pale yellow liquid
Uses(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4?-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
Uses(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction.
Synthesis Reference(s)Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0
General Description(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
Cylopropylmethyl chloride Preparation Products And Raw materials
Raw materialsCyclobutanol
Preparation Products4-CHLORO-1-BUTENE
Methylene Chloride Chloromethyl isopropyl carbonate Cylopropylmethyl chloride 3-Methyl-2-butanone Chloromethyl methyl ether 2-Chloro-5-chloromethylpyridine Calcium chloride Cyclopropanecarbonyl Chloride tert-Butyldimethylsilyl chloride Sodium chloride Ammonium chloride 3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarbonyl chloride (Bromomethyl)cyclopropane Cyclopropanecarboxylic acid 3-Chloropropyltrimethoxysilane 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile Chloromethane Allyl chloride

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