ChemicalBook Product Catalog Chemical Reagents Organic reagents Ethers (+)-CHLOROMETHYL MENTHYL ETHER

(+)-CHLOROMETHYL MENTHYL ETHER

(+)-CHLOROMETHYL MENTHYL ETHER Basic information
Product Name:(+)-CHLOROMETHYL MENTHYL ETHER
Synonyms:(1R,2S,4S)-2-(CHLOROMETHYLOXY)-1-ISOPROPYL-4-METHYLCYCLOHEXANE;(+)-CHLOROMETHYL MENTHYL ETHER;(+)-Chloromethyl menthyl ether, 97% ee;Cyclohexane, 2-(chloromethoxy)-4-methyl-1-(1-methylethyl)-, (1R,2S,4S)-
CAS:103128-76-3
MF:C11H21ClO
MW:204.74
EINECS:
Product Categories:Chiral Building Blocks;Ethers;Organic Building Blocks
Mol File:103128-76-3.mol
(+)-CHLOROMETHYL MENTHYL ETHER Structure
(+)-CHLOROMETHYL MENTHYL ETHER Chemical Properties
Boiling point 72 °C/0.4 mmHg (lit.)
density 0.994 g/mL at 25 °C (lit.)
refractive index n20/D 1.467(lit.)
Fp 225 °F
storage temp. -20°C
optical activity[α]24/D +181.0°, c = 2 in methylene chloride
CAS DataBase Reference103128-76-3
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(+)-CHLOROMETHYL MENTHYL ETHER Usage And Synthesis
Chemical Propertiesclear colorless liquid
Uses(+)-Chloromethyl menthyl ether can be used:
  • As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
  • As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
  • To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;5- C2H5)(PPh3)COCH3].

(+)-CHLOROMETHYL MENTHYL ETHER Preparation Products And Raw materials
(+)-CHLOROMETHYL MENTHYL ETHER (-)-CHLOROMETHYL MENTHYL ETHER (+)-MENTHYL CHLOROFORMATE (-)-CHLOROMETHYL MENTHYL ETHER (+)-Chloromethyl menthyl ether, 95%, 97% e.e. CHLOROMETHYL CYCLOHEXYL ETHER
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