Tetrahydrofuran-3-yl)methanamine

Tetrahydrofuran-3-yl)methanamine Basic information
Product Name:Tetrahydrofuran-3-yl)methanamine
Synonyms:3-Aminomethyl-THF;oxolan-3-ylmethylamine;C-(Tetrahydrofuran-3-yl)methylamine;(tetrahydro-3-furanylmethyl)amine(SALTDATA: FREE);C-(Tetrahydrofuran-3-yl)methylamine hydrochloride;(Tetrahydrofur-3-yl)methylamine;(TETRAHYDROFURAN-3-YL)METHANAMINE;TETRAHYDROFURAN-3-YLMETHYLAMINE
CAS:165253-31-6
MF:C5H11NO
MW:101.15
EINECS:676-405-7
Product Categories:
Mol File:165253-31-6.mol
Tetrahydrofuran-3-yl)methanamine Structure
Tetrahydrofuran-3-yl)methanamine Chemical Properties
Boiling point 156.0±13.0℃ (760 Torr)
density 0.967±0.06 g/cm3 (20 ºC 760 Torr)
refractive index n20/D1.462
Fp 53.1±13.1℃
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form Solution
pka9.96±0.29(Predicted)
color Clear colorless
InChIKeyCINJIXGRSTYIHP-UHFFFAOYSA-N
CAS DataBase Reference165253-31-6
Safety Information
Hazard Codes Xi
Risk Statements 10-37/38-41
Safety Statements 26-37/39
RIDADR 1993
WGK Germany 3
HazardClass 3
PackingGroup 
HS Code 29321900
MSDS Information
Tetrahydrofuran-3-yl)methanamine Usage And Synthesis
UsesTetrahydrofuran-3-yl)methanamine is an intermediate in the synthesis of Dinoteturan(D482100), a neonicotinoid insecticide.
Flammability and ExplosibilityNonflammable
SynthesisTetrahydrofuran-3-yl)methanamine,has been achieved through Michael addition reaction of nitromethane to diethyl maleate in 6 steps with 45.5% total yield.
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Tetrahydrofuran-3-yl)methanamine Preparation Products And Raw materials
Raw materialsNitromethane-->Diethyl maleate
4H-Furo(2,3-b)(1,5)benzodiazepin-4-one, 2,3,3a,5-tetrahydro-3a-ethyl-2 -methyl- Urea, 1-(3-ethyl-5-isopropyl-5-methyl-2-oxotetrahydro-3-furoyl)-3-phen yl- CBI-BB ZERO/005480 EXO-N-HYDROXY-7-OXABICYCLO[2.2.1]HEPT-5-ENE-2,3-DICARBOXIMIDE SALOR-INT L140678-1EA SQ 29,548 SQ 29548, [5,6-3H(N)]- 2-Oxo-N-phenyl-1-oxaspiro(4.5)decane-4-carboxamide N-(p-Fluorophenyl)-7-oxabicyclo(2.2.1)heptane-2,3-dicarboximide alpha-allyl-alpha-allophanyl-gamma-butyrolactone TOSLAB 701159 4-[3-(TRIFLUOROMETHYL)PHENYL]-10-OXA-4-AZATRICYCLO[5.2.1.0(2,6)]DEC-8-ENE-3,5-DIONE 4-(4-CHLOROPHENYL)-10-OXA-4-AZATRICYCLO[5.2.1.0(2,6)]DEC-8-ENE-3,5-DIONE 4-BENZYL-10-OXA-4-AZATRICYCLO[5.2.1.0(2,6)]DEC-8-ENE-3,5-DIONE TOSLAB 725764 2,3'-ANHYDROTHYMIDINE ENDOTHAL-PFPH (2',5'-bis-O-(tert-butyldimethylsilyl)-beta-ribofuranosyl)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole-2'',2''-dioxide)thymine

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