DAMASCONE

DAMASCONE Basic information
Product Name:DAMASCONE
Synonyms:1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-,(E)-2-Buten-1-one;1-[2,6,6-Trimethyl-1-cyclohexen-1-yl]-2-buten-1-one;(E)-β-damascone,(2E)-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-buten-1-one,trans-β-damascone;2-BUTEN-1-ONE, 1-(2,6,6-TRIMETHYLCYCLOHEX-1-ENYL)-, (E)-;TRANS-4-(2,6,6-TRIMETHYLCYCLOHEX-1-ENYL)-BUT-2-ENE-4-ONE;(E)-1-(2,6,6-Trimethyl-1-cyclohexen-1-yl)-2-buten-1-on;DAMASCON-BETA;DAMASCONE, B-(RG)
CAS:23726-91-2
MF:C13H20O
MW:192.3
EINECS:245-842-1
Product Categories:
Mol File:23726-91-2.mol
DAMASCONE Structure
DAMASCONE Chemical Properties
Boiling point 271℃
density 0.934 g/mL at 20 °C(lit.)
vapor pressure 2.6Pa at 25℃
FEMA 3243 | 1-(2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-YL)-2-BUTEN-1-ONE
refractive index n20/D 1.498
Fp 108℃
storage temp. -20°C
solubility Chloroform (Slightly), DMSO (Slightly)
form Oil
color Colourless to Pale Yellow
Odorat 1.00 % in dipropylene glycol. fruity floral berry plum blackcurrant honey rose tobacco
Odor Typefruity
Water Solubility 192.3mg/L(25 ºC)
JECFA Number384
BRN 2046078
Stability:Light Sensitive
LogP3.68
EPA Substance Registry System2-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (2E)- (23726-91-2)
Safety Information
Hazard Codes Xi
Risk Statements 43
Safety Statements 36/37
WGK Germany 2
RTECS EN0340000
10-23
HS Code 29142990
MSDS Information
ProviderLanguage
SigmaAldrich English
DAMASCONE Usage And Synthesis
Uses(E)-β-Damascone is an odorant found in some food, tea and tobacco plants. It is found to inhibit lipopolysaccharide mediated nitric oxide production through nuclear factor E2-related protein 2 signaling in human colon adenocarcinoma and mouse macrophage.
DefinitionChEBI: 4-(2,6,6-Trimethylcyclohex-1-enyl)but-2-en-4-one is an enone.
Synthesis Reference(s)Journal of the American Chemical Society, 94, p. 9128, 1972 DOI: 10.1021/ja00781a023
Flammability and ExplosibilityNonflammable
DAMASCONE Preparation Products And Raw materials
horminone 4-Acetoxy--damascone 4-Oxo-β-damascone DAMASCONE 3-Hydroxy-β-damascone 9-Hydroxy-8,9-dihydro-β-damascone DAMASCONE, DELTA 4-Hydroxy-β-damascone Beta-Damascone Delta Damascone (+/-)-ALPHA-DAMASCONE TRANS-ALPHA-DAMASCONE,trans-α-Damascone TRANS,TRANS-DELTA DAMASCONE BETA-CYCLOCITRAL CIS-ALPHA-DAMASCONE DAMASCONE(RG) 2-Hydroxy-β-damascone DAMASCONE(REAGENT / STANDARD GRADE)

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