ChemicalBook Product Catalog Chemical Reagents Organic reagents Tosylate TRIMETHYLSILYL METHANESULFONATE

TRIMETHYLSILYL METHANESULFONATE

TRIMETHYLSILYL METHANESULFONATE Basic information
Product Name:TRIMETHYLSILYL METHANESULFONATE
Synonyms:TRIMETHYLSILYL METHANESULFONATE;trimethylsilyl methanesulphonate;Methanesulfonic acid trimethylsilyl ester;Methylsulfonyloxytrimethylsilane;TriMethylsilyl Methanesulfonate,puruM;TriMethylsilyl Methanesulfonat;Trimethylsilyl mesylate;Silanol,1,1,1-trimethyl-, 1-methanesulfonate
CAS:10090-05-8
MF:C4H12O3SSi
MW:168.29
EINECS:233-220-2
Product Categories:Protecting and Derivatizing Reagents;Protection and Derivatization;Silicon-Based
Mol File:10090-05-8.mol
TRIMETHYLSILYL METHANESULFONATE Structure
TRIMETHYLSILYL METHANESULFONATE Chemical Properties
Melting point 103-104 °C
Boiling point 103-104 °C/25 mmHg (lit.)
density 1.09 g/mL at 25 °C (lit.)
refractive index n20/D 1.422(lit.)
Fp 30°C
storage temp. 2-8°C
form liquid
Specific Gravity0.826
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 2076698
Safety Information
Risk Statements 10
Safety Statements 23-24/25
RIDADR UN 3272 3/PG 2
WGK Germany 3
F 10-21
TSCA No
HazardClass 3.1
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
TRIMETHYLSILYL METHANESULFONATE Usage And Synthesis
UsesReactant or reagent involved in:
  • Reduction of esters to ethers using boron difluoride triflate etherate
  • Elimination of C(8)-functional groups via regioselective dehydration
  • Dealkylsilylation of alumazene derivatives
TRIMETHYLSILYL METHANESULFONATE Preparation Products And Raw materials
Preparation ProductsTRIMETHYLSILYL TRIFLUOROACETATE
N-Bromosuccinimide TRIMETHYLSILYL BROMOACETATE Boron trifluoride diethyl etherate TRIMETHYLSILYL TRIFLUOROACETATE hydroxytrimethylsilane TRIMETHYLOLPROPANE TRIS(3-MERCAPTOPROPIONATE) Chlorosulfonyl isocyanate TRIMETHYLSILYL METHANESULFONATE TRIMETHYLSILYL NONAFLUOROBUTANESULFONATE TRIFLUOROMETHANESULFONIC ACID DIETHYLISOPROPYLSILYL ESTER TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE Trifluoromethanesulfonic acid tert-butyldimethylsilyl ester TETRAFLUORO-2-(PENTAFLUOROETHOXY)ETHANESULFONIC ACID TRIMETHYLSILYL ESTER TRIMETHYLSILYLBENZENESULFONATE TrimethylSilyl Trifluoromethanesulfonate Triethylsilyl trifluoromethanesulfonate DIMETHYL-(2,3-DIMETHYL-2-BUTYL)SILYL TRIFLUOROMETHANESULFONATE TERT-BUTYLDIPHENYLSILYL TRIFLATE)
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