(+)-Diisopinocampheyl chloroborane

(+)-Diisopinocampheyl chloroborane Basic information
Product Name:(+)-Diisopinocampheyl chloroborane
Synonyms:(+)-BETA-CHLORODIISOPINOCAMPHEYLBORANE;(+)-B-CHLORODIISOPINOCAMPHENYLBORANE;(+)-B-CHLORODIISOPINOCAMPHEYLBORANE;(+)-B-DIISOPINOCAMPHEYL-CHLOROBORANE;(+)-IPC2BCL;(+)-Diisopinocampheylchloroborane;(+)-DIP CHLORIDE;(+)-DIP-CHLORIDE(TM)
CAS:112246-73-8
MF:C20H34BCl
MW:320.75
EINECS:
Product Categories:Asymmetric Synthesis;B (Classes of Boron Compounds);Boranes;Reduction;Synthetic Organic Chemistry;chiral
Mol File:112246-73-8.mol
(+)-Diisopinocampheyl chloroborane Structure
(+)-Diisopinocampheyl chloroborane Chemical Properties
Melting point 53-55 °C(lit.)
Boiling point 369.6±25.0 °C(Predicted)
density 0.91
Fp >230 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Almost colorless
InChIKeyPSEHHVRCDVOTID-YYNWCRCSSA-N
CAS DataBase Reference112246-73-8(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34-37
Safety Statements 26-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
10-21
HazardClass 8
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
(+)-Diisopinocampheyl chloroborane Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesBoth (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.
(+)-Diisopinocampheyl chloroborane Preparation Products And Raw materials
Preparation Products(+)-ISOPINOCAMPHEYLAMINE-->(+)-Ipc2B(allyl), 1M in dioxane
Methylene Chloride (+)-Diisopinocampheyl chloroborane Pentaborane Hexane Calcium chloride Borane-methyl sulfide complex CHLORODICYCLOHEXYLBORANE Disiamylborane Choline chloride Diborane Ammonium chloride HEXANES Polyvinyl chloride (1R)-(+)-TRANS-PINANE Potassium chloride Thionyl chloride 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile (-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE,(-)-Diisopinocampheyl chloroborane

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