(METHOXYMETHYL)TRIMETHYLSILANE

(METHOXYMETHYL)TRIMETHYLSILANE Basic information

Product Name:	(METHOXYMETHYL)TRIMETHYLSILANE
Synonyms:	trimethylsilyl methyl ether;Trimethyl(methoxymethyl)silane;Silane, (methoxymethyl)trimethyl-;TRIMETHYLSILYLMETHYL METHYL ETHER;(METHOXYMETHYL)TRIMETHYLSILANE;(METHOXYMETHYL)TRIMETHYLSILANE 95%;Methoxymethyltrimethylsilane>
CAS:	14704-14-4
MF:	C5H14OSi
MW:	118.25
EINECS:
Product Categories:	Synthetic Organic Chemistry;Biochemistry;Reagents for Oligosaccharide Synthesis;Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis)
Mol File:	14704-14-4.mol

(METHOXYMETHYL)TRIMETHYLSILANE Chemical Properties

Melting point	<0°C
Boiling point	83 °C/740 mmHg (lit.)
density	0.758 g/mL at 25 °C (lit.)
refractive index	n20/D 1.39(lit.)
Fp	8 °F
form	clear liquid
Specific Gravity	0.755
color	Colorless to Almost colorless
Hydrolytic Sensitivity	1: no significant reaction with aqueous systems
BRN	1732033
CAS DataBase Reference	14704-14-4(CAS DataBase Reference)
NIST Chemistry Reference	(Methoxymethyl)trimethylsilane(14704-14-4)

Safety Information

Hazard Codes	F,Xi
Risk Statements	11-36/37/38
Safety Statements	16-26-28-29-33-36/37/39
RIDADR	UN 3271 3/PG 2
WGK Germany	3
TSCA	No
HazardClass	3.1
PackingGroup	II
HS Code	29319090

MSDS Information

Provider	Language
SigmaAldrich	English

(METHOXYMETHYL)TRIMETHYLSILANE Usage And Synthesis

Purification Methods

It forms an azeotrope with MeOH (b 60o). If it contains MeOH (check IR for bands above 3000cm-1), then wash with H2O and fractionate. A possible impurity could be chloromethyl trimethylsilane (b 97o/740mm). [Speier J Am Chem Soc 70 4142 1948, Beilstein 4 III 1844.] It is an IRRITATING FLAMMABLE liquid.

(METHOXYMETHYL)TRIMETHYLSILANE Preparation Products And Raw materials

Raw materials	(TRIMETHYLSILYL)METHYL TRIFLUOROMETHANESULFONATE-->Methanol-->Dimethyl ether-->Sodium Methoxide-->Chloromethyltrimethylsilane-->Chloromethyl methyl ether-->Chlorotrimethylsilane
Preparation Products	METHYL FLUORIDE-->METHOXYTRIMETHYLSILANE

hydroxytrimethylsilane (METHOXYMETHYL)TRIMETHYLSILANE TRIMETHYLSILANE ACRYLOXYMETHYLTRIMETHYLSILANE METHACRYLOXYMETHYLTRIMETHYLSILANE (PHENYLDIMETHYLSILYL)METHYL METHACRYLATE (1-ETHOXYVINYL)-TRIMETHYLSILANE TRIMETHYLSILYLMETHYL ACETATE (2',5'-bis-O-(tert-butyldimethylsilyl)-beta-ribofuranosyl)-3'-spiro-5''-(4''-amino-1'',2''-oxathiole-2'',2''-dioxide)thymine (1-METHOXYVINYL)TRIMETHYLSILANE

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(METHOXYMETHYL)TRIMETHYLSILANE

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