1,1'-Bi-2-naphthol

1,1'-Bi-2-naphthol Basic information

Product Name:	1,1'-Bi-2-naphthol
Synonyms:	AURORA KA-7212;BI-2-NAPHTHOL;DI-B-NAPHTHOL;(R)-(+)-1,1'-BI(2,2'-NAPHTHOL);(+/-)-1,1A-Bi-2-naphthol;(+/-)-Binaphthalene-2,2-diol;(+/-)-BINOL;(+/-)-1,1'-BINAPHTHALENE-2,2'-DIOL
CAS:	602-09-5
MF:	C20H14O2
MW:	286.32
EINECS:	210-014-0
Product Categories:	Naphthalene derivatives;Aromatic Hydrocarbons (substituted) & Derivatives;Intermediates of Dyes and Pigments;API intermediates;Miscellaneous;bc0001;602-09-5
Mol File:	602-09-5.mol

1,1'-Bi-2-naphthol Chemical Properties

Melting point	215-218 °C
Boiling point	388.69°C (rough estimate)
density	1g/cm
refractive index	1.7580 (estimate)
storage temp.	Inert atmosphere,Room Temperature
solubility	Soluble in dioxane (50 mg/mL).
solubility	dioxane: 50 mg/mL, clear
pka	8.29±0.50(Predicted)
form	Powder
color	White to beige
Water Solubility	insoluble
Merck	14,1226
BRN	997518
InChIKey	PPTXVXKCQZKFBN-UHFFFAOYSA-N
CAS DataBase Reference	602-09-5(CAS DataBase Reference)
NIST Chemistry Reference	1,1'-Bi-2-naphthol(602-09-5)
EPA Substance Registry System	[1,1'-Binaphthalene]-2,2'-diol (602-09-5)

Safety Information

Hazard Codes	T,Xi
Risk Statements	25-36-36/37/38
Safety Statements	26-45-37/39-36
RIDADR	UN 2811 6.1/PG 3
WGK Germany	3
RTECS	DU3106100
F	10
TSCA	Yes
HazardClass	6.1
PackingGroup	III
HS Code	29072900
Toxicity	LDLo orl-mus: 42 mg/kg AECTCV 14,111,85

MSDS Information

Provider	Language
2,2'-Dihydroxy-1,1'-binaphthyl	English
SigmaAldrich	English
ACROS	English
ALFA	English

1,1'-Bi-2-naphthol Usage And Synthesis

Chemical Properties	1,1′-Bi-2-naphthol is a white to yellowish gray crystalline powder. It is known to be soluble in methanol. Store in a cool and dark place at ambient temperatures for best keeping.
Uses	1,1'-Bi-2-naphthol is used as a chiral ligand in alkynylation, Diels-Alder and assymmetric Michael addition reactions.
Uses	(+/-)-1,1'-Bi(2-naphthol) acts as chiral separation agents. It is widely used in chiral liquid crystal,medicines,spices etc,.
Uses	Chiral ligand and auxiliary for asymmetric Michael addition reaction; enantioselective Diels-Alder reaction; alkynylation.
Definition	ChEBI: (S)-(-)-1,1'-Bi-2-naphthol is a member of naphthols.
Synthesis Reference(s)	Tetrahedron, 48, p. 9483, 1992 DOI: 10.1016/S0040-4020(01)88316-2 Tetrahedron Letters, 24, p. 3261, 1983 DOI: 10.1016/S0040-4039(00)88151-4
Safety Profile	1,1'-Bi-2-naphthol is incompatible with oxidizing agents and should not be stored or handled near them. Poison by ingestion and causes skin irritation along with serious eye irritation. When heated to decomposition it emits acrid smoke and irritatingvapors.
Purification Methods	Crystallise the binaphthol from toluene or *benzene (10mL/g). When crystallised from chlorobenzene it has m 238o. Its solubility in dioxane is 5%. [Beilstein 6 IV 7020.]

1,1'-Bi-2-naphthol Preparation Products And Raw materials

Preparation Products

1.1'-Binaphthyl-2.2'-diphemyl phosphine-->2-BROMO-1,1-BINAPHTHYL-->DINAPHTHO[1,2-B:1',2'-D]FURAN-->2,2'-DIBROMO-1,1'-BINAPHTHYL-->(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL-->PORPHINE-->7H-DIBENZO[C,G]CARBAZOLE-->Ethanol, 2,2'-[(1R)-[1,1'-binaphthalene]-2,2'-diylbis(oxy)]bis--->PHOSPHINE OXIDE, [1,1'-BINAPHTHALENE]-2,2'-DIYLBIS-->2-CHLORO-1-(3-CHLORO-PHENYL)-ETHANOL

1-Naphthol 1,1'-Bi-2-naphthol Solvent Red 43 (S)-(+)1,1'-Bi-2-Naphthol Deacetate (R)-(+)-3,3'-Dibromo-5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2-naphthol,99% (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthalol, (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthol S-1,1-Bi-2-Naphthol(S-Binol) 3,3''-[OXYBIS(METHYLENE)]BIS-(1R,1''R)-1,1''-BI-2-NAPHTHOL 1,1'-BI-2-NAPHTHOL BIS(TRIFLUOROMETHANESULFONATE) p-Naphtholbenzein (R)-(-)1,1'-Bi-2-Naphthol Deacetate binaphthol ALPHA-NAPHTHOLBENZEIN (S)-(-)-1,1'-Bi-2-naphthol,(S)-1,1 -BI-2-NAPHTHOL ***REVERSE***,S-(-)-1,1'-Bi-2-naphthol,99%(S)-BINOL,(S)-(−)-1,1'-Bi(2-naphthol) (S)-3,3-DIBROMO-5,5'',6,6'',7,7'',8,8''-OCTAHYDRO-1,1''-BI-2-NAPHTHOL 99% Phenmedipham 2-Naphthol Terbinafine Hydrochloride

Email:[email protected] [email protected]

Copyright © 2024 Mywellwork.com All rights reserved.