ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic alcohol 2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL

2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL

2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL Basic information
Product Name:2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL
Synonyms:4-HYDROXY-3-METHOXYPHENYLBORONIC ACID, PINACOL CYCLIC ESTER;4-HYDROXY-3-METHOXYPHENYLBORONIC ACID PINACOL ESTER;2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL;2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol,min.97%;2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL, MIN. 97%;4-Hydroxy-3-methoxyphenylboronic acid, pinacol cyclic ester, 2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol;2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol,97%;2-Methoxy-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol4-Hydroxy-3-methoxyphenylboronic acid pinacol ester
CAS:269410-22-2
MF:C13H19BO4
MW:250.1
EINECS:
Product Categories:organic or inorganic borate;Boronic acids
Mol File:269410-22-2.mol
2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL Structure
2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL Chemical Properties
Melting point 105-109 °C(lit.)
Boiling point 367.3±32.0 °C(Predicted)
density 1.11±0.1 g/cm3(Predicted)
storage temp. Sealed in dry,2-8°C
form Crystalline Powder
pka9.66±0.35(Predicted)
color White to cream
CAS DataBase Reference269410-22-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL Usage And Synthesis
Chemical Propertieswhite to cream crystalline powder
Uses4-Hydroxy-3-methoxyphenylboronic acid pinacol ester can be used as a reactant:
  • In the Suzuki-Miyaura cross-coupling reaction.
  • To prepare ethylidenedihydroindolones as potential neoplastic agents.
  • To synthesize 5,6-dihydropyrrolo[2,1-b]isoquinoline derivatives, which can be utilized as scaffolds to prepare lamellarin analogs via regioselective bromination and Suzuki cross-coupling reactions.

Uses4-Hydroxy-3-methoxyphenylboronic acid, pinacol ester
2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL Preparation Products And Raw materials
Raw materials4-ACETYL-2-METHOXYPHENYL ACETATE-->4-Bromo-2-methoxyphenol-->Guaiacol-->Pinacolborane-->Bis(pinacolato)diboron
Orthoboric acid 2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL 3-BENZYLOXY-4-METHOXYBORONIC ACID, PINACOL ESTER 2-CHLORO-6-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL 2-[4-([1,3]DIOXOLAN-2-YLMETHOXY)-3-METHOXY-PHENYL]-4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLANE 4-BENZYLOXY-3-METHOXYBORONIC ACID, PINACOL ESTER 4-METHOXY-2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL 3-Methoxyphenylboronic acid 3-ACETOXY-4-METHOXYPHENYLBORONIC ACID, PINACOL ESTER 2-METHOXY-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENYL ACETATE 1,4-BENZODIOXANE-6-BORONIC ACID, PINACOL ESTER 4-(2-[2-METHOXY-4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-PHENOXY]-ETHYL)-MORPHOLINE 3-METHOXY-5-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PHENOL 3,4-METHYLENEDIOXYPHENYLBORONIC ACID, PINACOL ESTER 3,4-DIMETHOXYPHENYLBORONIC ACID, PINACOL ESTER
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