HEXANAMIDE

HEXANAMIDE Basic information
Product Name:HEXANAMIDE
Synonyms:N-HEXANAMIDE;N-CAPROIC AMIDE;N-CAPRONAMIDE;N-CAPROAMIDE;Capronamide;Hexamide;Hexoamide;Hexylamide
CAS:628-02-4
MF:C6H13NO
MW:115.17
EINECS:211-024-8
Product Categories:Color Former & Related Compounds;Functional Materials;Sensitizer
Mol File:628-02-4.mol
HEXANAMIDE Structure
HEXANAMIDE Chemical Properties
Melting point 100-102 °C(lit.)
Boiling point 215.49°C (rough estimate)
density 0.9990
refractive index 1.4200 (estimate)
pka16.76±0.40(Predicted)
form Flakes
color White to off-white
Water Solubility 29.72g/L(25 ºC)
Stability:Stable. Combustible. Incompatible with acids, bases, strong oxidizing agents.
CAS DataBase Reference628-02-4(CAS DataBase Reference)
EPA Substance Registry SystemHexanamide (628-02-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
RTECS MN7875000
TSCA Yes
HS Code 29241990
Hazardous Substances Data628-02-4(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
HEXANAMIDE Usage And Synthesis
Chemical Propertiescolourless crystalline solid
DefinitionChEBI: Hexanamide is a fatty amide of hexanoic acid. It is a primary carboxamide and a primary fatty amide. It is functionally related to a hexanoic acid.
Synthesis Reference(s)Canadian Journal of Chemistry, 45, p. 2599, 1967 DOI: 10.1139/v67-422
The Journal of Organic Chemistry, 49, p. 2015, 1984 DOI: 10.1021/jo00185a038
General DescriptionColorless crystals.
Air & Water ReactionsSlightly soluble in water.
Reactivity ProfileHEXANAMIDE is an amide. Amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx). Can react with mineral acids and bases.
Fire HazardFlash point data are not available for HEXANAMIDE, but HEXANAMIDE is probably combustible.
Purification MethodsRecrystallise the amide from hot water. [Beilstein 2 H 324, 2 I 141, 2 II 286, 2 III 732.]
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