Isopropyl tiglate

Isopropyl tiglate Basic information
Product Name:Isopropyl tiglate
Synonyms:isopropylalpha-methylcrotonate;isopropyl 2-methylcrotonate;ISOPROPYL TIGLATE 98+%;2-BUTENOICACID,2-METHYL-,1-ISOPROPYLESTER;(E)-Isopropyl 2-methylbutenoate;3-methylbut-2-enoic acid isopropyl ester;propan-2-yl 3-methylbut-2-enoate;2-Butenoic acid, 2-Methyl-, 1-Methylethyl ester, (2E)-
CAS:1733-25-1
MF:C8H14O2
MW:142.2
EINECS:217-067-9
Product Categories:Alphabetical Listings;Flavors and Fragrances;I-L
Mol File:1733-25-1.mol
Isopropyl tiglate Structure
Isopropyl tiglate Chemical Properties
Boiling point 199.78°C (rough estimate)
density 0.896 g/mL at 25 °C(lit.)
FEMA 3229 | ISOPROPYL TIGLATE
refractive index n20/D 1.431(lit.)
Fp 123 °F
Odorat 1.00 % in dipropylene glycol. sweet mint green vegetable spice
Odor Typeminty
JECFA Number312
LogP2.75
CAS DataBase Reference1733-25-1
NIST Chemistry ReferenceIsopropyl tiglate(1733-25-1)
EPA Substance Registry System2-Butenoic acid, 2-methyl-, 1-methylethyl ester, (2E)- (1733-25-1)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 16-26-36
RIDADR UN 3272 3/PG 3
WGK Germany 2
RTECS EM9254500
MSDS Information
ProviderLanguage
SigmaAldrich English
Isopropyl tiglate Usage And Synthesis
DescriptionIsopropyl tiglate is sweet, minty. It may be prepared by photolysis of 2,2,5,5-tetramethyldihydro-3-furanone in methanol; also by esterification of 3-methyl-2-butenoic acid with isopropyl alcohol in the presence of concentrated sulfuric acid.
Chemical PropertiesIsopropyl tiglate has a sweet, minty odor
PreparationBy photolysis of 2,2,5,5-tetramethyldihydro-3-furanone in methanol; also by esterification of 3-methyl-2-butenoic acid with isopropyl alcohol in the presence of concentrated sulfuric acid.
DefinitionChEBI: Isopropyl tiglate is a fatty acid ester.
Taste threshold valuesTaste characteristics at 30 ppm: green, minty and vegetative.
Isopropyl tiglate Preparation Products And Raw materials
Preparation ProductsFEMA 3699
Isopropyl palmitate Methyl ISOPROPYL LAURATE Bensulfuron methyl Maleic acid Titanium tetraisopropanolate Tiglic acid Kresoxim-methyl Isopropyl acetate 2-Methyl-2-butene Thiophanate-methyl 2,2-Dimethyl-1,3-dioxane-4,6-dione Methyl salicylate Methyl acrylate Isopropyl alcohol Methyl bromide 2-Hydroxypropyl methacrylate Isopropyl myristate

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