Pigment Green 18

Pigment Green 18 Basic information
Product Name:Pigment Green 18
Synonyms:TETRAMETHYLDI-P-AMINOTRIPHENYLCARBINOL CHLORIDE;S NO 754;VICTORIA GREEN G;HIDACO MALACHITE GREEN BASE;FAST GREEN O;FAST GREEN;CI 10000;CI NO 42000
CAS:569-64-2
MF:C23H25ClN2
MW:364.91
EINECS:209-322-8
Product Categories:Triphenylmethane;Biological stain;UVCBs-inorganic;Organics;Amines;Aromatics;Dyes and Pigments
Mol File:569-64-2.mol
Pigment Green 18 Structure
Pigment Green 18 Chemical Properties
Melting point 158-160°C
Boiling point 520.91°C (rough estimate)
density 1.0448 (rough estimate)
refractive index 1.5940 (estimate)
storage temp. Refrigerator
solubility Very soluble in water; soluble in ethanol, methanol, amyl alcohol
Colour Index 42000
form Solid
pka6.90(at 25℃)
color Brown
PH Range0(green)-2(green-blue)
λmax615nm, 425nm
BRN 3580148
Stability:Stable. Substances to be avoided include strong oxidizing agents.
Major ApplicationPhotoresists, color filter, printed circuit board, sol-gel matrix, liquid crystal displays, decoder system, inks, highlighters, herbicides, disinfectants, cosmetics, identifying mammal genes, detecting nucleic acids, mycobacterial growth, radiochemotherapy, wound dressing materials, antitumor agents, treatment of patients with pulmonary tuberculosis Malachite Green
Biological ApplicationsAntiseptic formulation; detecting nucleic acids; early diagnosis of tuberculosis; identifying mammal genes; treating cancers,fungal diseases,pulmonary tuberculosis; medical device
InChIKeyFDZZZRQASAIRJF-UHFFFAOYSA-M
LogP0.620
CAS DataBase Reference569-64-2
EPA Substance Registry SystemMalachite green (569-64-2)
Safety Information
Hazard Codes Xn,N
Risk Statements 22-41-50/53-63
Safety Statements 26-36/37/39-46-60-61-39-36/37
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
RTECS BQ1190000
HazardClass 9
PackingGroup III
HS Code 29215900
Hazardous Substances Data569-64-2(Hazardous Substances Data)
ToxicityLD50 oral in mouse: 80mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
Pigment Green 18 Usage And Synthesis
Chemical PropertiesGreen crystals. Soluble in water; ethyl, methyl, and amyl alcohol.
UsesA triphenylmethane dye with fungicidal and limited antiseptic activity. The term Malachine green applies to the oxalate as well as the chloride. Harmful if swallowed. Avoid release to the environment.
DefinitionChEBI: An organic chloride salt that is the monochloride salt of malachite green cation. Used as a green-coloured dye, as a counter-stain in histology, and for its anti-fungal properties in aquaculture.
Preparationcommonly known as Malachite Green. (a) in the presence of hydrochloric acid or sulfuric acid, Benzaldehyde ?(1 Moore) and N,N-dimethylaniline(2 Moore) condensation, and then used lamps and acid oxidation its products; (b) N,N-dimethylaniline and 1-(Trichloromethyl)benzene?heating.
General DescriptionGreen crystals with metallic luster. Water solutions are blue-green. Used in dyeing silk, wool, biological staining, etc.
Air & Water ReactionsVery soluble in water.
Reactivity ProfilePigment Green 18 neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
HazardToxic by ingestion.
Properties and Applicationsbright blue light green. Green belt flash crystallization. Soluble in cold water and hot water are blue-green, easily soluble in ethanol are blue-green. The strong sulfuric acid for yellow, diluted into dark orange; In nitric acid to orange, diluted into orange brown. The dye solution to join sodium hydroxide formation microstrip green white precipitation; Add hydrochloric acid to red light yellow. Used in acrylic, silk, wool, vinegar fiber dyeing, also used in leather, hemp, bamboo, wood, paper, shading, also used in the manufacture color amylum, solvent dye
Standard Light Fastness Persperation Fastness Ironing Fastness Soaping
Fading Stain Fading Stain Fading Stain
ISO 3 4-5 4-5 4 5 4-5 4-5
AATCC 2-3
Pigment Green 18 Preparation Products And Raw materials
Raw materialsSodium sulfate-->N,N-Dimethylaniline-->Sodium chlorate-->N-Methylaniline-->hypochlorous acid-->Lead dioxide-->Triton X-100
MALACHITE GREEN PDR MALACHITE GREEN G,ASTRA-DIAMOND GREEN GX,DIAMOND GREEN,DIAMOND GREEN G ALKALI FAST GREEN 10GA MALACHITE GREEN CARBINOL HYDROCHLORIDE,MALACHITE GREEN CARBINOL HYDROCHLORIDE TELON FAST GREEN 5G Nitro Fast Green GB,Organol Fast Green J MALACHITE GREEN G,DIAMOND GREEN,ASTRA-DIAMOND GREEN GX,DIAMOND GREEN G DIAMOND GREEN P EXTRA,MALACHITE GREEN,DIAMOND GREEN B,DIAMOND GREEN BX,TB-COLOR MALACHITE GREEN-(OXALATE),MALACHITE GREEN OXALATE SALT,MALACHITE GREEN OXALATE LUXOL FAST GREEN D5-LEUCO-MALACHITE GREEN ALIZARINE FAST GREEN MALACHITE GREEN CRY PONTAMINE FAST GREEN GL MALACHITE GREEN SOLUTION ACCORDING TO SCHAEFFER AND FULTON MALACHITE GREEN BASE,MALACHITE GREEN CARBINOL BASE ACILAN FAST GREEN 10G ALIZARINE FAST GREEN CGN EX PONTAMINE FAST GREEN 5BL

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