3,4,7,8-Tetramethyl-1,10-phenanthroline

3,4,7,8-Tetramethyl-1,10-phenanthroline Basic information
Description Reference
Product Name:3,4,7,8-Tetramethyl-1,10-phenanthroline
Synonyms:1,2,7,8-Tetramethyl-4,5-diazaphenanthrene;3,4,7,8-TetraMethyl -1,10-phenathroline;3,4,7,8-TetraMethyl-1,10-phenanthroline, 99+% 1GR;3,4,7,8-TETRAMETHYL-1,10-PHENANTHROLINE;TIMTEC-BB SBB008945;3,4,7,8-tetramethyl-10-phenanthroline;3,4,7,8-TETRAMETHYL-1,10-PHENANTHROLINE, 99+%;3,4,7,8-Tetramethyl-1,10-phenaanthroline
CAS:1660-93-1
MF:C16H16N2
MW:236.31
EINECS:216-762-4
Product Categories:Electronic Chemicals;Building Blocks;Chemical Synthesis;Heterocyclic Building Blocks;Heterocyclic Building Blocks;N-Containing;Others
Mol File:1660-93-1.mol
3,4,7,8-Tetramethyl-1,10-phenanthroline Structure
3,4,7,8-Tetramethyl-1,10-phenanthroline Chemical Properties
Melting point 277-280 °C(lit.)
Boiling point 368.78°C (rough estimate)
density 1.0937 (rough estimate)
refractive index 1.5635 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility Soluble in 1,4-dioxane, acetone, dichloromethane, N,N-dimethylformamide, N,N-dimethylacetamide, methanol and hot toluene.
pka6.37±0.10(Predicted)
form Fine Crystalline Powder
color Light beige
Water Solubility 1.512mg/L(25.04 ºC)
BRN 171279
InChIKeyNPAXPTHCUCUHPT-UHFFFAOYSA-N
CAS DataBase Reference1660-93-1(CAS DataBase Reference)
EPA Substance Registry System1,10-Phenanthroline, 3,4,7,8-tetramethyl- (1660-93-1)
Safety Information
Hazard Codes Xn
Risk Statements 36/37/38-20/21/22-40
Safety Statements 36/37/39-26-36-22-24/25
WGK Germany 3
TSCA Yes
HS Code 29339900
MSDS Information
ProviderLanguage
3,4,7,8-Tetramethyl-1,10-phenanthroline English
SigmaAldrich English
ACROS English
ALFA English
3,4,7,8-Tetramethyl-1,10-phenanthroline Usage And Synthesis
Description

3,4,7,8-Tetramethyl-1,10-phenanthroline is used as a metal-chelating agent. For instance, it is used in the synthesis of heteroleptic cationic Ir(III) complex: 3,4,7,8-tetramethyl-1,10-phenanthroline-bis[2-(2’,4’-difluorophenyl)pyridine]iridium(III) hexafluorophosphate. It is used as a ligand to form dinuclear Cu(II) hypocrelin B complexes. It also forms tetraaqua(3,4,7,8-tetramethyl-1,10-phenanthroline-kappa2N,N′)zinc(II) thiosulfate complex with zinc.

Reference

Y. Sun, YJ. Hou, QX. Zhou, WH. Lei, JR. Chen, XS. Wang, BW. Zhang, Dinuclear Cu(II) hypocrellin B complexes with enhanced photonuclease activity, Inorganic Chemistry, 2010, vol. 49, pp. 10108-10116

Chemical Propertieslight beige fine crystalline powder
Uses3,4,7,8-Tetramethyl-1,10-phenanthroline is a metal-chelating agent.
3,4,7,8-Tetramethyl-1,10-phenanthroline Preparation Products And Raw materials
3,4,7,8-Tetramethyl-1,10-phenanthroline 1,7-PHENANTHROLINE 4,7-Dimethyl-1,10-phenanthroline 3,4-DIMETHYLQUINOLINE Quinoline N,N,N',N'-Tetramethylethylenediamine 3,3',5,5'-Tetramethylbenzidine dihydrochloride o-Phenanthroline Octamethylcyclotetrasiloxane 3-Picoline 3-Methylquinoline Tetramethylsilane Poly(tetrahydrofuran) 3,4,7,8-TETRAMETHYL-1,10-PHENANTHROLINE FERROUS SULFATE 4-METHYL-1,10-PHENANTHROLINE Tetrakis(hydroxymethyl)phosphonium sulfate Hexamethylenetetramine 3,4-Lutidine

Email:[email protected] [email protected]
Copyright © 2024 Mywellwork.com All rights reserved.