ChemicalBook Product Catalog Organic Chemistry Amides Acyclic polyamines and their derivatives BREDERECK'S REAGENT

BREDERECK'S REAGENT

BREDERECK'S REAGENT Basic information
Product Name:BREDERECK'S REAGENT
Synonyms:tert-Butoxy bis(dimethylamino)methane technical;T-BUTOXYBIS(DIMETHYLAMINO)METHANE;TERT-BUTOXYBIS(DIMETHYLAMINO)METHANE;BREDERECKS REAGENT;BREDERECK'S REAGENT;BUTOXYBIS(DIMETHYLAMINO)METHANE;tert-Butoxybis(dimethylamino)methane, 85+%;Bis(dimethylamino)(tert-butoxy)methane
CAS:5815-08-7
MF:C9H22N2O
MW:174.28
EINECS:227-383-9
Product Categories:Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Polyamines;Elisa Kit-plant ELISA Kit
Mol File:5815-08-7.mol
BREDERECK'S REAGENT Structure
BREDERECK'S REAGENT Chemical Properties
Boiling point 50-55 °C/15 mmHg (lit.)
density 0.844 g/mL at 25 °C (lit.)
refractive index n20/D 1.422(lit.)
Fp 106 °F
storage temp. Sealed in dry,Store in freezer, under -20°C
solubility Chloroform (Sparingly), DMSO (Sparingly), Methanol (Slightly)
pka5.46±0.38(Predicted)
form Liquid
color Clear pale yellow
Specific Gravity0.844
BRN 1901973
Stability:Hygroscopic
InChIInChI=1S/C9H22N2O/c1-9(2,3)12-8(10(4)5)11(6)7/h8H,1-7H3
InChIKeyHXRAMSFGUAOAJR-UHFFFAOYSA-N
SMILESC(OC(C)(C)C)(N(C)C)N(C)C
CAS DataBase Reference5815-08-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,F
Risk Statements 10-36/37/38
Safety Statements 26
RIDADR UN 1993 3/PG 3
WGK Germany 3
F 10
HazardClass 3
PackingGroup III
HS Code 29221990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
BREDERECK'S REAGENT Usage And Synthesis
Chemical PropertiesClear pale yellow liquid
UsesReactant for:• ;Preparation of pyrroloquinazolines as photochemotherapeutic agents1• ;Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition2• ;Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction3• ;Aminomethylenation reactions4
UsesMild enamination reagent; catalyst in ring-opening polymerization reactions.
UsesReactant for:
  • Preparation of pyrroloquinazolines as photochemotherapeutic agents
  • Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition
  • Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction
  • Aminomethylenation reactions
BREDERECK'S REAGENT Preparation Products And Raw materials
Preparation Products5-METHOXY-1H-PYRROLO[3,2-B]PYRIDINE-->Cyclohexaneacetic acid, 4-[4-[(1Z)-1-cyano-2-(diMethylaMino)ethenyl]phenyl]-, ethyl ester, trans--->2-Propen-1-one, 1-cyclohexyl-3-(dimethylamino)-, (E)- (8CI)-->3-(dimethylamino)-1,2-diphenyl-2-propen-1-one-->EthenaMine, 2-(2-benzoxazolyl)-N,N-diMethyl--->5-[(DIMETHYLAMINO)METHYLENE]-3-PHENYL-2-THIOXOTETRAHYDRO-4H-IMIDAZOL-4-ONE-->2-(2-BROMOPYRIDIN-4-YL)ACETONITRILE
TERT-BUTYL VINYL ETHER 2,6-DIMETHYL-4-NITROSOPHENOL tert-Butyldimethylsilyl chloride Poly(vinyl alcohol) Selenium dioxide TERT-BUTYL 4-(2-HYDROXYETHYL)PIPERAZINE-1-CARBOXYLATE Trisodium citrate dihydrate BREDERECK'S REAGENT METHOXY-BIS(DIMETHYLAMINO)METHANE
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