5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE

5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Basic information
Product Name:5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE
Synonyms:5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE;5,10,15,20-TETRAPHENYL-21H,23H-PORPHYRIN IRON(III) CHLORIDE;MESO-TETRAPHENYLPORPHYRIN IRON(III) CHLORIDE;MESO-TETRAPHENYLPORPHYRIN IRON(III) CHLORIDE COMPLEX;IRON TPP;IRON (III) MESO-TETRAPHENYLPORPHINE CHLORIDE;IRON (III) TETRAPHENYLPORPHINE CHLORIDE;RARECHEM AS SA 0004
CAS:16456-81-8
MF:C44H28ClFeN4
MW:704.03
EINECS:
Product Categories:metal porphine (porphyrin) complex
Mol File:16456-81-8.mol
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Structure
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Chemical Properties
Melting point 300 °C
storage temp. Inert atmosphere,Room Temperature
form crystal
color purple
Water Solubility Insoluble in water.
Stability:Stable. Incompatible with strong oxidizing agents, strong acids.
InChIKeyZDYSAMCSFRQDMN-XBZZRTMISA-M
CAS DataBase Reference16456-81-8
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 29349990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Usage And Synthesis
Chemical Propertiesdark red or purple powder
UsesIron(III) meso-tetraphenylporphine chloride is used catalyzing reagent for silylation reactions.
Purification MethodsPurify it by extraction from a thimble (Soxhlet) with CHCl3. Concentrate the extract to ca 10mL and add ca 80mL of hot MeOH. Dark blue crystals separate on cooling. It can be recrystallised several times from CHCl3/MeOH. Avoid prolonged heating. It is quite soluble in organic solvents but insoluble in pet ether. [Rothemund & Manotti J Am Chem Soc 70 1808 1948, UV: Dorough et al. J Am Chem Soc 73 4315 1951, Beilstein 26 III 1960.]
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE Preparation Products And Raw materials
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE IRON(III) CHLORIDE 5,10,15,20-TETRAKIS-(4-AMINOPHENYL)-PORPHYRIN-FE(III) CHLORIDE 5-(4-HYDROXYMETHYLPHENYL)-10,15,20-TRIPHENYL-PORPHYRIN-FE(III) CHLORIDE 5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE 5,10,15,20-TETRAKIS-(4-CARBOXYPHENYL)-PORPHYRIN-FE-(III) CHLORIDE RARECHEM AS SA 0018 5,10,15,20-TETRAKIS-(3-METHOXY-4-HYDROXY-PHENYL)-PORPHYRIN-FE(III) CHLORIDE FETPPS 5,10,15,20-TETRAKIS-(3-HYDROXYPHENYL)-PORPHYRIN-FE(III) CHLORIDE 5-(3-HYDROXYPHENYL)-10,15,20-TRIPHENYL-PORPHYRIN-FE(III) CHLORIDE 5-(4-CARBOXYPHENYL)-10,15,20-TRIPHENYL-PORPHYRIN-FE(III) CHLORIDE 5,10,15,20-TETRAKIS-(4-HYDROXYPHENYL)-PORPHYRIN-FE(III) CHLORIDE 5-(4-HYDROXYPHENYL)-10,15,20-TRIPHENYL-PORPHYRIN-FE(III) CHLORIDE 5,10,15,20-TETRAKIS-(2,6-DICHLOROPHENYL)-PORPHYRIN-FE(III) CHLORIDE 5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE 5,10,15,20-TETRAKIS-(4-METHOXYCARBONYLPHENYL)-PORPHYRIN-FE(III) CHLORIDE 5,10,15,20-TETRAKIS-(4-BROMOPHENYL)-PORPHYRIN-FE-(III) CHLORIDE 2-AMINO-5,10,15,20-TETRAPHENYLPORPHYRIN-FE(III) CHLORIDE

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