2,6-Dichloro-4-nitroaniline

2,6-Dichloro-4-nitroaniline Basic information
Product Name:2,6-Dichloro-4-nitroaniline
Synonyms:Resisan;Resissan;u-2069;DICLORAN, 1GM, NEAT;DICHLORAN PESTANAL (2,6-DICHLORO- 4-NITR;2,6-Dichloro-4-nitroaniline, tech., 97%;2,6-Dichloro-4-nitro-1-aminobenzene;dichloran (canada)
CAS:99-30-9
MF:C6H4Cl2N2O2
MW:207.01
EINECS:202-746-4
Product Categories:Pharmaceutical intermediate;Intermediates of Dyes and Pigments;99-30-9
Mol File:99-30-9.mol
2,6-Dichloro-4-nitroaniline Structure
2,6-Dichloro-4-nitroaniline Chemical Properties
Melting point 190-192 °C (lit.)
Boiling point 130°C 2mm
density 1.6257 (rough estimate)
vapor pressure 1.6 x 10-4 Pa (20 °C)
refractive index 1.6560 (estimate)
Fp 130°C/2mm
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility 0.006g/l (HSDB)
pkapK1:-3.31(+1) (25°C)
form neat
color Light Yellow to Yellow
Water Solubility 1 g/L (60 ºC)
BRN 1459581
LogP2.800
CAS DataBase Reference99-30-9(CAS DataBase Reference)
NIST Chemistry Reference2,6-Dichloro-4-nitroaniline(99-30-9)
EPA Substance Registry SystemDichloran (99-30-9)
Safety Information
Hazard Codes Xi,Xn,N,T+
Risk Statements 33-36/37/38-20/21/22-51/53-26/27/28
Safety Statements 22-26-36-37/39-61-45-36/37-28
RIDADR 2811
WGK Germany 3
RTECS BX2975000
TSCA Yes
HazardClass 6.1(b)
PackingGroup III
HS Code 29214210
Hazardous Substances Data99-30-9(Hazardous Substances Data)
MSDS Information
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2,6-Dichloro-4-nitroaniline Usage And Synthesis
Chemical Propertiesyellow granular powder and chunks
Chemical PropertiesDicloran is a yellow crystalline solid or power. Odorless.
UsesDichloran is a component for pesticide formulations.
UsesDicloran is a protectant fungicide used to control various rots pathogens (Botrytis, Monilinia, Rhizopus and Sclerotinia) in a wide variety of fruits and vegetables.
UsesIt is used as dyestuff, agricultural and pharmaceutical intermediate.
DefinitionChEBI: A nitroaniline that is 4-nitroaniline in which the hydrogens at positions 2 and 6 are replaced by chlorines. An agricultural fungicide, it is not approved for use in the European Union.
Agricultural UsesFungicide: Used to control fungi on a variety of crops. The top crop usages in California are on celery, head lettuce, and grapes (table, wine and raisin). Not approved for use in EU countries. Actively registered in the U.S. Sixty-five global suppliers.
Trade nameAL-50®; ALLISAN®; BORTRAN®; BOTRAN®; DITRANIL®; FUMITE DICLORAN SMOKE ACARICIDE®; RESISAN®; RD-6584®; U-2069®
Potential ExposureDichloran is a substituted benzene/ chlorophenyl fungicide Used to control fungi on a variety of crops. The top crop usages in California are on celery, head lettuce, and grapes (table, wine and raisin).
Metabolic pathwayThe metabolism of 2,6-dichloro-4-nitroaniline (DCNA) in rat hepatic microsomes gives rise to the unique metabolite 3,5-dichloro-4-aminophenol (DCAP).
ShippingUN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required
Purification MethodsCrystallise Dichloran from aqueous EtOH or *benzene/EtOH. [Beilstein 12 IV 1681.]
DegradationDicloran (1) is stable to hydrolytic degradation (pH 5-9) up to 300 °C. Degradation occurred when dicloran in pH 7 solution was irradiated with UV light (>290 nm); the estimated DT50 was 41 days (PM). Smith-Downey and Fordham (1990) reported the hydrolysis of dicloran in 6 M base to yield 3,5-dichloro-4-aminophenol(2) as the only product detected.
IncompatibilitiesKeep away from strong oxidizing agents, strong acids; acid anhydrides; acid chlorides; acetic anhydride; and carbon dioxide
Waste DisposalConsult with a licensed waste disposal service or environmental regulatory agencies for guidance on acceptable disposal practices. Dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber
Nitroaniline DICHLORAN ROSE BENGAL AGAR (BASE) FOR N-Methyl-4-nitroaniline 3,5-dichloro-2-nitroaniline,3,5-dichloro-2-nitroaniline 4-Chloro-2-nitroaniline Dichloran Medium Base w/ Rose Bengal 3,4-DICHLORO-2-NITROANILINE,3,4-DICHLORO-2-NITROANILINE N1-BENZYL-2,3-DICHLORO-6-NITROANILINE, TECH,N1-BENZYL-2,3-DICHLORO-6-NITROANILINE, TECH 2-Chloro-4-nitroaniline 2-Nitroaniline 2,5-DICHLORO-4-NITROANILINE,2,5-DICHLORO-4-NITROANILINE DICHLORO BENZIDINE DI HYDROCHLORIDE (DCB) 2,6-DICHLORO-4-NITROANILINE, [14C(U)],2,6-DICHLORO-4-NITROANILINE, [14C(U)] 3,5-DICHLORO-4-NITROANILINE,3,5-DICHLORO-4-NITROANILINE 3-Nitroaniline 2,6-Dichloroaniline 4-Nitroaniline 2,6-Dichloro-4-nitroaniline

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