Palmitic acid ethyl ester

Palmitic acid ethyl ester Basic information
Product Name:Palmitic acid ethyl ester
Synonyms:Ethyl palmita;HEXADECANOIC ACID ETHYL ESTER;Ethyl cetylate;ETHYL HEXADECANOATE;ETHYL PALMITATE;ETHYL N-HEXADECANOATE;FEMA 2451;Ethyl palmitate, (Ethyl hexadecanoate
CAS:628-97-7
MF:C18H36O2
MW:284.48
EINECS:211-064-6
Product Categories:Fatty Acid Derivatives & Lipids;Glycerols;Inhibitors
Mol File:628-97-7.mol
Palmitic acid ethyl ester Structure
Palmitic acid ethyl ester Chemical Properties
Melting point 24-26 °C (lit.)
Boiling point 192-193 °C/10 mmHg (lit.)
density 0.857 g/mL at 25 °C (lit.)
vapor pressure 0.01Pa at 25℃
FEMA 2451 | ETHYL PALMITATE
refractive index n20/D 1.440(lit.)
Fp >230 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form neat
Specific Gravity0.857
color Colourless to Off-White
Odorat 100.00 %. mild waxy fruity creamy milky balsamic greasy oily
Odor Typewaxy
Water Solubility IMMISCIBLE
JECFA Number39
BRN 1782663
LogP7.74
CAS DataBase Reference628-97-7(CAS DataBase Reference)
NIST Chemistry ReferenceHexadecanoic acid, ethyl ester(628-97-7)
EPA Substance Registry SystemHexadecanoic acid, ethyl ester (628-97-7)
Safety Information
Hazard Codes Xi
Safety Statements 23-24/25
WGK Germany 3
Hazard Note Irritant
TSCA Yes
HS Code 29157020
MSDS Information
ProviderLanguage
Palmitic acid ethyl ester English
SigmaAldrich English
ACROS English
ALFA English
Palmitic acid ethyl ester Usage And Synthesis
DescriptionPalmitic acid ethyl ester, also known as ethyl palmitate, it the ethyl ester form of palmitic acid. It can be used as a hair- and skin-conditioning agent. It has been shown that the combination between palmitic acid ethyl ester and cobra venom factor can enhance the survival of heterologous erythrocyte. Recent study has also demonstrated the potential anti-inflammatory activity of palmitic acid ethyl ester in several animal models.
Chemical Propertiesclear colorless oily liquid after melting
Chemical PropertiesEthyl palmitate has a mild, waxy sweet odor. It is nearly tasteless and has a creamy mouthfeel.
OccurrenceReported found in mutton, rye bread, rice, bourbon, vanilla, red sage, lemon balm, bilberry, Parmesan cheese, maple syrup, Jamaican rum, whiskey, grape wine, cognac, cocoa, green tea, mango, corn oil and mastic gum leaf oil.
UsesEthyl palmitate acts as a lubricant on the skin?s surfaces in order to get a soft and smooth appearance. It increases cytosolic Ca2+ concentration leading to pancreatic acinar cell injury due to excessive consumption of ethanol.
UsesA fatty acid found in Amaranth oil; it shows inhibitory activity.
DefinitionChEBI: A long-chain fatty acid ethyl ester resulting from the formal condensation of the carboxy group of palmitic acid with the hydroxy group of ethanol.
Aroma threshold valuesDetection: 2 ppm
Taste threshold valuesTaste characteristics at 30 ppm: waxy, fruity, creamy and fermented with a vanilla, balsamic nuance.
Synthesis Reference(s)Tetrahedron, 48, p. 8775, 1992 DOI: 10.1016/S0040-4020(01)89450-3
General DescriptionEthyl palmitate is a one of the major volatile compounds found in cooked rice and Luzhou-flavor raw liquor. It occurs naturally in licorice root and chamomile.
SynthesisSynthesized by immobilized lipase-catalyzed alcoholysis and esterification in organic solvents.
ReferencesBeste, Russell D, and R. D. Hamlin. "Skin permeation enhancer compositions comprising a monoglyceride and ethyl palmitate." US, US6267984. 2001.
Castro, O, et al. "Mechanism of ethyl palmitate and cobra venom factor enhancement of heterologous erythrocyte survival. " Proceedings of the Society for Experimental Biology & Medicine Society for Experimental Biology & Medicine 147.1(1974):106.
Saeed, N. M., et al. "Anti-inflammatory activity of methyl palmitate and ethyl palmitate in different experimental rat models. " Toxicology & Applied Pharmacology 264.1(2012):84-93.

Palmitic acid ethyl ester Preparation Products And Raw materials
Preparation ProductsHEXADECANAMIDE-->Ethanol
Isopropyl palmitate Vitamin A palmitate TRIACONTANOIC ACID ETHYL ESTER DIETHYL N-HEXADECYLMALONATE STEARIC ANHYDRIDE Span 60 BEHENIC ANHYDRIDE Cholesteryl palmitate OCTADECYLSUCCINIC ANHYDRIDE 3-alpha-Ethoxycarbonyl-12-alpha-hydroxy-7-oxocholan-24-oic acid, methy l ester Madecassoside N-TETRADECYLSUCCINIC ANHYDRIDE Palmitic anhydride N-HEXADECYLSUCCINIC ANHYDRIDE TRIPALMITIN CHOLESTERYL STEARATE ETHYL STEARATE ETHYL CHAULMOOGRATE

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