Platinum bis(acetylacetonate)

Platinum bis(acetylacetonate) Basic information
Product Name:Platinum bis(acetylacetonate)
Synonyms:4-pentanedionato-o,o’)-bis((sp-4-1)-platinu;Bis(2,4-pentanedionato-O,O')platinum;2,4-Pentanedione platinum(II) derivative, Pt(acac)2;Platinum(II) acetylacetonate,2,4-Pentanedione platinum(II) derivative, Pt(acac)2;Platinum(Ⅱ) 2,4-pentanedionate, Pt 48.0% min;PlatinuM(Ⅱ) 2,4-pentanedionate;PlatinuM(II) acetylacetonate,98% Pt(CH3COCHCOCH3)2;Acetylacetone Platinum(II) Salt Platinum(II) Acetylacetonate
CAS:15170-57-7
MF:C10H14O4Pt
MW:393.29
EINECS:239-223-5
Product Categories:chemical reaction,pharm,electronic,materials;Synthetic Organic Chemistry;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Transition Metal Compounds;Metal Complexes;Pt (Platinum) Compounds
Mol File:15170-57-7.mol
Platinum bis(acetylacetonate) Structure
Platinum bis(acetylacetonate) Chemical Properties
Melting point 249-252 °C(lit.)
Fp 170°C
storage temp. Store below +30°C.
solubility soluble in Acetone
form Powder
color Yellow to yellow-green
Specific Gravity2.336
Water Solubility insoluble
Sublimation 170 ºC
BRN 4136189
NIST Chemistry ReferencePlatinum bis(acetylacetonate)(15170-57-7)
EPA Substance Registry SystemPlatinum, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (15170-57-7)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38-63
Safety Statements 26-36/37/39
WGK Germany 3
10
TSCA Yes
HS Code 3815 90 90
ToxicityLD50 orally in Rabbit: > 500 mg/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Platinum bis(acetylacetonate) Usage And Synthesis
Chemical Propertiesyellow to yellow-green powder
UsesUsed for photoactivated hydrosilylation reactions between vinyl and silane groups; in the deposition of platinum metal and in the preparation of platinum nanotubes. Precursor for FePt superlattice magnetic nanoparticles.
Purification MethodsIt crystallises from *C6H6 as yellow crystals and is dried in air or in a vacuum desiccator. [Werner Chem Ber 34 2584 1901, Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 H 783, 1 IV 3678.]
Platinum bis(acetylacetonate) Preparation Products And Raw materials
VANADIUM(III) ACETYLACETONATE Vanadyl acetylacetonate Ferric acetylacetonate 1-BUTENE TRANS-2-PENTENE Acetylacetone Propane titanium (Ⅳ) acetylacetonate Crotonaldehyde PROPYLENE vinyl alcohol PLATINUM(II)HEXAFLUOROACETYLACETONATE Water Pentane METHANOL WITH FORMALDEHYDE Methyl vinyl ketone Acetaldehyde Zinc(II) acetylacetonate

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