Benzophenone imine

Benzophenone imine Basic information
Product Name:Benzophenone imine
Synonyms:Benzophenone imine ,98%;Benzophenone imine ,97%;1-naphtholphthalein.BenzophenoneiMine;6-benzoylcyclohexa-2,4-dien-1-iMine;Benzophenone iMine, stabilized, 97% 100GR;Benzophenone iMine, stabilized, 97% 5GR;1,1-Diphenylmethylimine, Benzophenone imine, 1,1-Diphenylmethanimine;DiphenylMethaniMineiMine
CAS:1013-88-3
MF:C13H11N
MW:181.23
EINECS:440-870-2
Product Categories:Pharmaceutical Intermediates;B;Stains and Dyes;Stains&Dyes, A to;Aromatic Building Blocks
Mol File:1013-88-3.mol
Benzophenone imine Structure
Benzophenone imine Chemical Properties
Melting point -30 °C
Boiling point 151-153 °C10 mm Hg(lit.)
density 1.08 g/mL at 25 °C(lit.)
vapor pressure 0.082Pa at 20℃
refractive index n20/D 1.618(lit.)
Fp 145 °C
storage temp. Inert atmosphere,Room Temperature
solubility DMSO (Slightly), Ethyl Acetate (Slightly)
pkapK1:6.82 (25°C)
form Liquid
color Clear colorless to light yellow-brownish
Water Solubility 0.3 g/L (25 ºC)
BRN 1100371
InChIKeySXZIXHOMFPUIRK-UHFFFAOYSA-N
CAS DataBase Reference1013-88-3(CAS DataBase Reference)
NIST Chemistry ReferenceBenzenemethanimine, «alpha»-phenyl-(1013-88-3)
Safety Information
Hazard Codes Xi,N,Xn
Risk Statements 36/37/38-51/53-38-22
Safety Statements 26-36-61-37
RIDADR UN3082
WGK Germany 3
HS Code 29252900
MSDS Information
ProviderLanguage
Benzophenone imine English
SigmaAldrich English
ACROS English
Benzophenone imine Usage And Synthesis
Chemical Propertiesclear colorless to light yellow-brownish liquid
UsesBenzophenone imine is useful in the preparation of nitrile ylide dimers.
UsesUseful in the preparation of nitrile ylide dimers.Benzophenone imine as ammonia surrogate. As intermediate material for synthesis of organic chemicals. Catalytic enantioselective alkylation of the benzophenone imine of glycine t-butyl ester using phosphazene (Schwesinger) bases and chiral quaternary ammonium salts yields either enantiomer of amino acid derivatives in excellent yield.
Synthesis Reference(s)Synthetic Communications, 18, p. 1501, 1988 DOI: 10.1080/00397918808081307
Flammability and ExplosibilityNotclassified
Benzophenone hydrazone O-Phthalimide 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid 10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-one oxime 5H-dibenzo[a,d]cyclohepten-5-one oxime 4-Chlorobenzophenone Benzophenone oxime 1-[(2-Chlorophenyl)-N-(methylimino)methyl]cyclopentanol hydrochloride Yellow pyoctanine Imipenem Benzophenone 2,2',4,4'-Tetrahydroxybenzophenone N-(Diphenylmethylene)aminoacetonitrile 9-FLUORENONE OXIME Oxybenzone (+),(-)-A-2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOOXYPROPIONIC ACID Ethyleneimine Benzophenone imine

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