p-Toluoyl chloride

p-Toluoyl chloride Basic information

Product Name:	p-Toluoyl chloride
Synonyms:	4-methylbenzoicacidchloride;4-methyl-benzoylchlorid;Benzoyl chloride, 4-methyl-;p-Toluoyl chlori;p-Toluoyl chloride 98%;The Methyl benzoyl chloride;P-methbenzoylchloride;4-Methylbenzenecarbonyl chloride
CAS:	874-60-2
MF:	C8H7ClO
MW:	154.59
EINECS:	212-864-8
Product Categories:	Acid Halides;Building Blocks;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Pyridines;ACIDHALIDE;874-60-2
Mol File:	874-60-2.mol

p-Toluoyl chloride Chemical Properties

Melting point	-4--2 °C (lit.)
Boiling point	225-227 °C (lit.) 95-96 °C/10 mmHg (lit.)
density	1.169 g/mL at 25 °C (lit.)
vapor density	5.33 (vs air)
vapor pressure	0.55 mm Hg ( 20 °C)
refractive index	n20/D 1.553(lit.)
Fp	180 °F
storage temp.	Store below +30°C.
form	Liquid
Specific Gravity	1.169
color	Clear colorless to slightly brown
PH	1 (H2O, 20℃)
explosive limit	1.6%, 117°F
Water Solubility	Reacts with water alcohol.
Sensitive	Moisture Sensitive
BRN	471492
CAS DataBase Reference	874-60-2(CAS DataBase Reference)
NIST Chemistry Reference	4-Methylbenzoic acid chloride(874-60-2)
EPA Substance Registry System	Benzoyl chloride, 4-methyl- (874-60-2)

Safety Information

Hazard Codes	C
Risk Statements	34
Safety Statements	26-36/37/39-45-24/25
RIDADR	UN 3265 8/PG 2
WGK Germany	3
RTECS	XV1660000
TSCA	Yes
HazardClass	8
PackingGroup	II
HS Code	29163900

MSDS Information

Provider	Language
4-Methylbenzoyl chloride	English
SigmaAldrich	English
ACROS	English
ALFA	English

p-Toluoyl chloride Usage And Synthesis

Chemical Properties	CLEAR COLOURLESS TO SLIGHTLY BROWNISH LIQUID
Uses	Intermediates of Liquid Crystals
Uses	p-Toluoyl chloride was used to prepare antigen, Tolyl-amido-human serum albumin. It is used as a reagent to synthesize (+)-Yashabushitriol, derivatives of Desloratadine.
General Description	p-Toluoyl chloride causes the benzoylation of toluene using triflic acid funtionalized mesoporous Zr-TMS catalysts. It causes1,9-diacylation of a dipyrromethane using the hindered Grignard reagent 2,6-dimethylphenylmagnesium bromide.

p-Toluoyl chloride Preparation Products And Raw materials

Raw materials	p-Toluic acid-->(4-METHYLPHENYL)-1,2-ETHANEDIOL-->4-Methylbenzyl alcohol-->4-Methyl-benzoic acid tert-butyl ester-->4-Iodobenzoyl chloride-->4-Iodotoluene-->carbon monoxide-->4-Bromotoluene-->4-Iodoanisole-->P-XYLENE-->Butyryl chloride-->Terephthaloyl chloride-->p-Tolualdehyde
Preparation Products	4-METHYLHIPPURIC ACID-->4-(BROMOMETHYL)-N-(L-METHYLETHYL)BENZAMIDE-->2-(4-METHYLPHENYL)-BENZOTHIAZOLE-->p-Tolyl isocyanate-->1-Iodo-4-nitrobenzene-->4-METHYLPHTHALIMIDE 99-->4,N-DIMETHYL-N-METHOXYBENZAMIDE

6-Chloro-2-fluoro-3-methylbenzoyl chloride, 97+% 4-FLUORO-2-METHYLBENZOYL CHLORIDE 3-ACETOXY-2-METHYLBENZOYL CHLORIDE, CH3CO2 2,3,5-trifluoro-4-methylbenzoyl chloride 2-Chloro-6-fluoro-3-methylbenzoyl chloride, 97+% 2-hydroxy-5-methylbenzoyl chloride 4-Fluoro-2-methylbenzoyl chloride 99%,4-FLUORO-2-METHYLBENZOYL CHLORIDE 99 2-hydroxy-4-methylbenzoyl chloride 3-FLUORO-5-METHYLBENZOYL CHLORIDE 3-hydroxy-4-methylbenzoyl chloride M-METHYLBENZOYL CHLORIDE,3-METHYLBENZOYL CHLORIDE,3-METHYLBENZOYL CHLORIDE / M-TOLUOYL CHLORIDE 3-FLUORO-2-METHYLBENZOYL CHLORIDE 3,5-Dinitro-2-Methylbenzoyl Chloride Benzoyl chloride, 4-ethenyl- (9CI) 2-FLUORO-4-METHYLBENZOYL CHLORIDE 5-BROMO-2-METHOXY-3-METHYLBENZOYL CHLORIDE 4-Fluoro-3-methylbenzoyl chloride 98%,4-FLUORO-3-METHYLBENZOYL CHLORIDE,4-Fluoro-3-methylbenzoyl chloride, 97+% 5-FLUORO-2-METHYLBENZOYL CHLORIDE,5-Fluoro-2-methylbenzoyl chloride 97%

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