ChemicalBook Product Catalog Pharmaceutical intermediates (R)-MONOPHOS

(R)-MONOPHOS

(R)-MONOPHOS Basic information
Product Name:(R)-MONOPHOS
Synonyms:3,4-a']dinaphthalen-4-yl)dimethylamine,min.97%(S)-MONOPHOS;(S)-(+)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1'',2''-F][1,3,2]DIOXAPHOSPHEPIN (S)-MONOPHOS;(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (S)-MONOPHOS;(S)-(+)-[4-N,N-Dimethylamino]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(S)-(+)-[4-N,N-DIMETHYLAMINO]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPINE;(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DI-NAPHTHALEN-4-YL)DIMETHYLAMINE;(R)-MONOPHOS;(S)-MONOPHOS
CAS:185449-80-3
MF:C22H18NO2P
MW:359.36
EINECS:
Product Categories:Chiral Phosphine;CPN
Mol File:185449-80-3.mol
(R)-MONOPHOS Structure
(R)-MONOPHOS Chemical Properties
Melting point 190 °C (dec.)
alpha +587° (c 0.06, CHCl3)
Boiling point 548.7±33.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
pka1.22±0.20(Predicted)
color white
Sensitive moisture sensitive
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 2929.90.5090
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-MONOPHOS Usage And Synthesis
Uses1. Asymmetric hydrogenation of ketones and β-keto esters.
2. Light-induced, enantioselective hydrogenation.
UsesDSM MonoPhos Family of Highly Efficient Privileged Ligands
(R)-MONOPHOS Preparation Products And Raw materials
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT 3,4-a']dinaphthalen-4-yl)dimethylamine (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)[(1R)-1-PHENYLETHYL]AMINE CYTOSINEARABINOSIDE,CYTOSINEARAB.MONOPHOS.,CYT.ARAB.TRIPHOS.,SHEEPANTI- 8-bromoadenosine 3',5'-cyclic monophos-phoric aci,8-BROMOADENOSINE 3',5'-CYCLIC MONOPHOS-P HORIC ACID, NA SALT MONOHYDRATE, 98% DSM MONOPHOS? LIGAND KIT DSM MONOPHOS TM LIGAND KIT CYCLIC-ADENOSINE-5'-MONOPHOS-PHATE-AGAROSE
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