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| Zirconyl chloride octahydrate Basic information | Synthesis |
Product Name: | Zirconyl chloride octahydrate | Synonyms: | Zirconium(Ⅳ)oxychloride octahydrate;zirconyl(di)chloride;ZIRCONYL CHLORIDE TECHNICAL;Zirconyl chloride oc;ZirconiuM Chloride octahydrate;Zirconyl chloride octahydrate, 98+% 100GR;Zirconyl chloride octahydrate, 98+% 5GR;Zirconyl Chloride, Octahydrate, Reagent, ACS | CAS: | 13520-92-8 | MF: | Cl2H2O2Zr | MW: | 196.14 | EINECS: | 603-909-6 | Product Categories: | 13520-92-8 | Mol File: | 13520-92-8.mol | |
| Zirconyl chloride octahydrate Chemical Properties |
Melting point | 400°C (dec.) | Boiling point | 210°C | density | 1.91 | storage temp. | Store at +15°C to +25°C. | solubility | H2O: soluble | form | Crystalline Powder | color | White to light yellow | Specific Gravity | 1.91 | Odor | Odorless | PH | 1 (50g/l, H2O, 20℃) | Water Solubility | SOLUBLE | Sensitive | Hygroscopic | Merck | 14,10184 | Exposure limits | ACGIH: TWA 5 mg/m3; STEL 10 mg/m3 NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 | Stability: | Stable, but may be moisture sensitive. Incompatible with strong oxidizing agents. | CAS DataBase Reference | 13520-92-8(CAS DataBase Reference) |
Hazard Codes | C | Risk Statements | 34-22-37 | Safety Statements | 26-36/37/39-45-27 | RIDADR | UN 3264 8/PG 3 | WGK Germany | 1 | RTECS | ZH7250000 | TSCA | Yes | HS Code | 2827 49 90 | HazardClass | 8 | PackingGroup | III | Toxicity | LD50 orally in Rabbit: 3500 mg/kg |
| Zirconyl chloride octahydrate Usage And Synthesis |
Synthesis | Zircon is melted with caustic soda, rinsed, desiliconized, and then reacted with sulfuric acid, and then ammonia water is added to obtain zirconium hydroxide precipitate. Finished zirconium oxychloride. | Chemical Properties | solid | Uses | Zirconium dichloride oxide is utilized as a precursor to prepare other zirconium compounds. It is employed in acid dyes, pigment toners and antiperspirants. It finds application as a rubber additive and a fiber treatment agent. It is also used in paint drying, refractories, ceramics and glaze. | General Description | This product is used as a potential green catalyst. | Purification Methods | Recrystallise the chloride several times from water [Ferragina et al. J Chem Soc, Dalton Trans 265 1986]. Recrystallisation from 8M HCl gives the octahydrate as white needles on concentrating. It is also formed by hydrolysing ZrCl4 with water. After one recrystallisation from H2O, 99+% grade zirconyl chloride had Ag, Al, As, Cd, Cu, Hf, Mg, Na, Sc and V at 20, 1.8, 0.6, 0.6, 0.4, 8.4, 0.4, 2.4, 80 and 3 ppm, respectively. (See above.) METAL-ORGANIC COMPOUNDS This section contains metal-organic compounds as well as ammonium and metal salts of organic acids. (For Introduction see p 445.) |
| Zirconyl chloride octahydrate Preparation Products And Raw materials |
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