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| | (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Basic information | | Reaction |
| Product Name: | (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE | | Synonyms: | MANDYPHOS SL-M003-1;(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE;(aR,aR)-1,1#-Bis[-(dimethylamino)benzyl]-(S,S)-2,2#-bis{bis[3,5-bis(trifl;(S,S)-(-)-2,2'-Bis((R)-(N,N-dimethylamino)-(phenyl)methyl)-1,1'-di(bis(3,5-trifluoromethylphenyl)phosphino)ferrocene;(R,R)-1,1'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]-2,2'-BIS[(R)-ALPHA-(DIMETHYLAMINO)BENZYL]FERROCENE;(S,S)-(-)-2,2'-BIS[(R)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-DI[BIS(3,5-TRIFLUOROMETHYLPHENYL)PHOSPHINO]FERROCENE;(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis[di(3,5-trifluoromethylphenyl)phosphino]ferrocene,min.97%;(r,r)-1,1'-bis{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2,2'-bis[(r)-α-(dimethylamino)benzyl]ferrocene (acc to cas) | | CAS: | 494227-36-0 | | MF: | C60H42F24FeN2P210* | | MW: | 1364.74 | | EINECS: | | | Product Categories: | Chiral Phosphine;Ferrocene Series;Mandyphos Series | | Mol File: | 494227-36-0.mol | ![(ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Structure](CAS/GIF/494227-36-0.gif) |
| | (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Chemical Properties |
| alpha | -250.2° (c 1.0, CHCl3) | | form | solid | | color | orange-red | | Stability: | store cold |
| | (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Usage And Synthesis |
| Reaction |
- Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates.
- Ligand for Rh-catalyzed hydrogenation of αand β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3diketones.
- Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives.
- Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones.
- Ligand for Cu-catalyzed enantioselective hydroboration of αand β-unsaturated esters and nitriles.
| | Chemical Properties | Orange powder |
| | (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-,2'-BIS[BIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINO]FERROCENE Preparation Products And Raw materials |
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