(2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE

(2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE Basic information
Product Name:(2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE
Synonyms:2-(tert-Butyldimethylsilyloxy)-1-bromoethane;2-(tert-Butyldimethylsilyloxy)bromoethane;2-(tert-Butyldimethylsilyloxy)ethyl bromide;2-Bromoethyl tert-butyldimethylsilyl ether;(1-(2-BroMoethoxy)-2-Methylpropan-2-yl)diMethylsilane;Silane,(2-broMoethoxy)(1,1-diMethylethyl)diMethyl-;(2-BroMoethoxy)-tert-butyldiMethylsilane 99%;(2-BroMoethoxy)-tert-butyldiMethylsilane, 98%+
CAS:86864-60-0
MF:C8H19BrOSi
MW:239.23
EINECS:
Product Categories:Miscellaneous;Organic Building Blocks;Oxygen Compounds;Protected Alcohols/Phenols
Mol File:86864-60-0.mol
(2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE Structure
(2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE Chemical Properties
Boiling point 70-75 °C2.5 mm Hg(lit.)
density 1.115 g/mL at 25 °C(lit.)
refractive index n20/D 1.444(lit.)
Fp 163 °F
storage temp. 2-8°C
form Liquid
Specific Gravity1.115
color White to pale yellow
Hydrolytic Sensitivity7: reacts slowly with moisture/water
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
(2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE Usage And Synthesis
Chemical Propertiescolorless liquid
Uses(2-Bromoethoxy)-tert-butyldimethylsilane can be used in N-alkylation with 5-piperazin-1-yl-1H-indole to synthesize 5-(4-(2-((tert-butyldimethylsilyl)oxy)ethyl)piperazin-1-yl)-1H-indole.
Uses(2-Bromoethoxy)-tert-butyldimethylsilane was used in the synthesis of 4-(3-hydroxypropyl)-4′-methyl-2,2′-bipyridine.
It may be used as a reagent for the selective N-alkylation of 5-piperazin-1-yl-1H-indole and (1H-indol-2-yl)-piperazin-1-yl-methanone and also in the synthesis of 2-[3-[(3,4,5-trimethoxyphenyl)thio]-1H-indol-5-yloxy]ethanol.
General Description(2-Bromoethoxy)-tert-butyldimethylsilane is a silane derivative.
(2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE Preparation Products And Raw materials
Raw materialsImidazole
Preparation ProductsBIS(2-((TERT-BUTYLDIMETHYLSILYL)OXY)ETHYL)AMINE
DISILANE Ethanol Hydroxy silicone oil Dimethyldimethoxysilane 1,2-Bis(chlorodimethylsilyl)ethane 1-Cyclohexenyloxytrimethylsilane Sodium nitrite DIMETHYLSILANE (2-METHYLALLYLOXY)TRIMETHYLSILANE, 95% (2-BROMOPHENYLETHYNYL)TRIMETHYLSILANE Hexamethylcyclotrisiloxane TERT-BUTYL 4-AMINO-3-FLUOROPIPERIDINE-1-CARBOXYLATE (3-PHENYLPROPYL)METHYLDICHLOROSILANE T-BUTYLDIMETHYLSILANE METHYL (S)-(-)-4-BROMO-3-TERT-BUTYLDIMETHYLSILYLOXYBUTANOATE METHYLSILANE TERT-BUTYLDIMETHYLSILYL BROMOACETATE (2-BROMOETHOXY)-TERT-BUTYLDIMETHYLSILANE

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