(-)-Diisopinocampheyl chloroborane

(-)-Diisopinocampheyl chloroborane Basic information
Product Name:(-)-Diisopinocampheyl chloroborane
Synonyms:(-)-diisopinocampheylchloroborane,(-)-dpc,inheptanes;(-)-diisopinocampheylchloroborane,(-)-dpc,inhexanes;(-)-BETA-CHLORODIISOPINOCAMPHEYLBORANE;(-)-B-DIISOPINOCAMPHEYL-CHLOROBORANE;(-)-B-CHLORODIISOPINOCAMPHENYLBORANE;(-)-DIP-CHLORIDE(TM);(-)-Diisopinocampheylchloroborane, in hexanes, 2M solution;(-)-Diisopinocampheylchloroborane, in heptanes, 2M solution
CAS:85116-37-6
MF:C20H34BCl
MW:320.75
EINECS:237-458-8
Product Categories:Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Asymmetric Synthesis;B (Classes of Boron Compounds);Boranes;Reduction;Synthetic Organic Chemistry
Mol File:85116-37-6.mol
(-)-Diisopinocampheyl chloroborane Structure
(-)-Diisopinocampheyl chloroborane Chemical Properties
Melting point 52-56 °C(lit.)
Boiling point 66-69°C
density 0.954 g/mL at 25 °C
refractive index -51 ° (C=neat)
Fp 82 °F
storage temp. Inert atmosphere,2-8°C
form clear liquid
color Colorless to Almost colorless
BRN 5937756
CAS DataBase Reference85116-37-6(CAS DataBase Reference)
Safety Information
Hazard Codes C,F+,N,F
Risk Statements 34-20/22-12-10-67-65-62-51/53-48/20-50/53-11-37
Safety Statements 9-16-29-33-36/37-61-62-45-36/37/39-26
RIDADR UN 3261 8/PG 2
WGK Germany 3
10-21
HazardClass 3/8
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
(-)-Diisopinocampheyl chloroborane Usage And Synthesis
Chemical Propertiessolutio
UsesBoth (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.
(-)-Diisopinocampheyl chloroborane Preparation Products And Raw materials
Raw materials(-)-Diisopinocampheyl borane-->(1R)-(+)-ALPHA-PINENE
Preparation Products(-)-ISOPINOCAMPHEYLAMINE
Boron Borane-pyridine complex Pentaborane Benzyl chloride Calcium chloride Borane-methyl sulfide complex Acetyl chloride Methoxydiethylborane CHLORODICYCLOHEXYLBORANE Disiamylborane Choline chloride o-Carborane Diborane (1R)-(+)-CIS-PINANE Ammonium chloride Potassium chloride 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile (-)-Diisopinocampheyl chloroborane

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