BENZYL PHENYL ETHER

BENZYL PHENYL ETHER Basic information
Product Name:BENZYL PHENYL ETHER
Synonyms:(Phenoxymethyl)-benzene;alpha-Phenylanisole;Anisole, alpha-phenyl-;Ether, benzyl phenyl;PHENYL BENZYL ETHER;TIMTEC-BB SBB008247;BENZYL PHENYL ETHER;BENZYLOXY-BENZENE
CAS:946-80-5
MF:C13H12O
MW:184.23
EINECS:
Product Categories:Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:946-80-5.mol
BENZYL PHENYL ETHER Structure
BENZYL PHENYL ETHER Chemical Properties
Melting point 39-41 °C (lit.)
Boiling point 286-287 °C (lit.)
density 1.0120 (rough estimate)
refractive index 1.5641 (estimate)
Fp >230 °F
storage temp. Inert atmosphere,2-8°C
form Chunks
color Light brown-orange
Water Solubility Insoluble in water.
BRN 2045713
CAS DataBase Reference946-80-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29093090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
BENZYL PHENYL ETHER Usage And Synthesis
Chemical PropertiesLight brown-orange chunks
UsesBenzyl phenyl ether reacts with aluminum bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities.
General DescriptionBenzyl phenyl ether is a reactive organic oxygenate, containing ether as functional group, present in subbituminous and bituminous coals. It reacts with aluminium bromide in chlorobenzene solution to afford a mixture of phenol, o-benzyl phenol and dichlorodiphenylmethane. It is a useful as model compound in catalytic chemistry to represent the a-O4 ether bond in lignin and coal. It contains a weak ether bond of 234kJ/mol and belongs to the most thermo-labile compounds in lignin and low rank coal. Influence of alkali carbonates, common additives in biomass conversion, on the reaction pathways of BPE in superheated water has been reported. Cesium-exchanged heteropolyacid catalyzed decomposition of benzyl phenyl ether to aromatics has been investigated. Photo-Claisen rearrangements of benzyl phenyl ether was investigated in cation-exchanged Y zeolites and polyethylenes of differing crystallinities.
3,5-Dibenzyloxyacetophenone 3-BENZYLOXYBENZYL ALCOHOL 4-CYANOPHENYL 4-N-BUTYLBENZOATE PHENYL 3-HYDROXY-2-NAPHTHOATE 4-[4-(3,4-dihydro-2(1H)-isoquinolinylcarbonyl)-2-quinolinyl]benzyl phenyl ether 4-(Benzyloxy)benzyl chloride H-TYR(BZL)-OH 4-BENZYLOXY-3-METHOXYBENZALDEHYDE 4-CYANOPHENYL 4-HEPTYLBENZOATE 3,4-Dibenzyloxybenzaldehyde 3-(1,3-benzothiazol-2-yl)benzyl phenyl ether fomocaine (4-(1-methyl-3-(morpholin-4-yl)propyl)benzyl)-phenyl-ether [4-[1-Methyl-3-(morpholine-4-yl)propyl]benzyl]phenyl ether fomocaine (4-(2-methyl-3-(morpholin-4-yl)propyl)benzyl)-phenyl-ether Phenyl benzoate 4-BENZYLOXY-3-METHOXYBENZYL ALCOHOL Estradiol benzoate 1-benzyl-2-(3-bromopropoxy)benzene

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