Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide

Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide Basic information
Product Name:Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide
Synonyms:Diphenyl(2,4,6-trimethylbenzoyl);Diphenyl-(2,4,6-Trimethylbenzolyl)-Phosphine Oxide(SP-2,4,6);YF-PI TPO;diphenyl(2,4,6-trimethylbenzoyl)phosphine;IHT-PI TPO;Diphenyl(2,4,6-trimethylbenzoyl)phosphinoxid;2,4,6-Trimethyl-benzoyl-diphenyl-;biphenyl(2,4,6-trimethyl-benzoyl)-phosphine oxide
CAS:75980-60-8
MF:C22H21O2P
MW:348.37
EINECS:278-355-8
Product Categories:chemical additive;Miscellaneous;Organic Photoinitiators;Polymerization Initiators;Functional Materials;Photopolymerization Initiators;TPO;bc0001;75980-60-8
Mol File:75980-60-8.mol
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide Structure
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide Chemical Properties
Melting point 88-92 °C(lit.)
Boiling point 519.6±60.0 °C(Predicted)
density 1.12 g/mL at 25 °C(lit.)
vapor pressure 0Pa at 25℃
refractive index n20/D 1.475(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility soluble in Methanol
form powder to crystal
color Light yellow to Yellow to Green
Water Solubility 3.4mg/L at 20℃
λmax400nm(DMF)(lit.)
Stability:Stable. Incompatible with strong oxidizing agents.
InChIKeyVFHVQBAGLAREND-UHFFFAOYSA-N
LogP3.1 at 23℃
CAS DataBase Reference75980-60-8(CAS DataBase Reference)
EPA Substance Registry SystemPhosphine oxide, diphenyl(2,4,6-trimethylbenzoyl)- (75980-60-8)
Safety Information
Hazard Codes Xn,N
Risk Statements 22-62-51/53
Safety Statements 22-24/25-61-36/37
RIDADR UN 3077 9 / PGIII
WGK Germany 2
RTECS SZ0395000
HazardClass 9
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide Usage And Synthesis
Chemical Propertieswhite or cream powder
UsesTPO can be used in the photo-crosslinking of PMMA composite, which can further be used as a gate insulator in organic thin film transistors (OTFTs). It can also be used in the formation of UV curable urethane-acrylate coatings. It may also be used in the photoinduced reaction for the formation of organophosphine compounds, which potentially find their usage as ligands with metal catalysts and reagents.
UsesDiphenyl(2,4,6-trimethylbenzoyl)phosphine oxide is a photo initiator, used in many kinds of ink industries
General DescriptionDiphenyl(2,4,6-trimethylbenzoyl)phosphine oxide (TPO) is a monoacylphosphine oxide based photoinitiator that can be incorporated in a variety of polymeric matrixes for efficient curing and color stability of the resin.
Flammability and ExplosibilityNonflammable
Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide Preparation Products And Raw materials
Preparation ProductsEthyl 2,4,6-trimethylbenzoate
Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide 2-Methyl-4'-(methylthio)-2-morpholinopropiophenone 2-Hydroxy-4'-(2-hydroxyethoxy)-2-methylpropiophenone Boron oxide Diphenylphosphine oxide (Diethoxymethyl)diphenylphosphine oxide Iron oxide DIPHENYL(2,4,6-TRIMETHYLBENZOYL)PHOSPHINE OXIDE/2-HYDROXY-2-METHYL-PROPIOPHENONE Benzyltrimethylammonium hydroxide Triethyl phosphonoacetate NITRIC OXIDE Chlorodiphenylphosphine Tetramethylammonium hydroxide pentahydrate Rutile NITROUS OXIDE Triphenylphosphine oxide Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide Iron oxide black

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