ChemicalBook Product Catalog Organic Chemistry Phosphines DIETHYLPHENYLPHOSPHINE

DIETHYLPHENYLPHOSPHINE

DIETHYLPHENYLPHOSPHINE Basic information
Product Name:DIETHYLPHENYLPHOSPHINE
Synonyms:Diethylphenylphosphene;Phosphine, diethylphenyl-;DIETHYLPHENYLPHOSPHINE;Diethylphenylphosphine ,96%;Phenyldiethylphosphine;diethyl(phenyl)phosphane;NSC 158475;Diethylphenylphosphine >
CAS:1605-53-4
MF:C10H15P
MW:166.2
EINECS:216-516-6
Product Categories:Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphines (Mitsunobu Reaction);Mitsunobu Reaction;Phosphine Ligands;Phosphorus Compounds;Synthetic Organic Chemistry
Mol File:1605-53-4.mol
DIETHYLPHENYLPHOSPHINE Structure
DIETHYLPHENYLPHOSPHINE Chemical Properties
Melting point 45 °C
Boiling point 120-121 °C/29 mmHg (lit.)
density 0.954 g/mL at 25 °C (lit.)
refractive index n20/D 1.546(lit.)
Fp 185 °F
form Liquid
color Colorless to Light yellow
Specific Gravity0.954
Water Solubility Not miscible or difficult to mix in water.
Sensitive Air & Moisture Sensitive
BRN 742484
CAS DataBase Reference1605-53-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 17-26-36
RIDADR UN3278
WGK Germany 3
F 10
HazardClass 6.1
PackingGroup III
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
DIETHYLPHENYLPHOSPHINE Usage And Synthesis
Chemical PropertiesColorless liquid
UsesDiethylphenylphosphine is used as a catalyst for selective cross-dimerization, carboxyl migration reactions, selective hydrogenation, asymmetric induction by chiral diphosphines in ring contraction.
DIETHYLPHENYLPHOSPHINE Preparation Products And Raw materials
Raw materialsDiethyl ether-->Nitrogen-->Magnesium-->Bromoethane-->Dichlorophenylphosphine
(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE DIBUTYLPHENYLPHOSPHINE DI-N-PENTYLPHENYLPHOSPHINE (+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE BIS(2-CYANOETHYL)PHENYLPHOSPHINE BIS(3-AMINOPROPYL)PHENYLPHOSPHINE Dicyclohexylphenylphosphine (+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE DIALLYLPHENYLPHOSPHINE 3-METHYL-1-PHENYL-3-PHOSPHOLENE 1-OXIDE AURORA KA-1754 DI-TERT-BUTYLPHENYLPHOSPHINE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE (-)-TETRAPHOS Octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide DIETHYLPHENYLPHOSPHINE
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