RUTHENIUM CARBONYL

RUTHENIUM CARBONYL Basic information
Reactions
Product Name:RUTHENIUM CARBONYL
Synonyms:dodecacarbonyltri-rutheniutriangulo;Ru3(CO)12;TrirutheniuM dodecacarbonyl 99%;Trirutheniumdodecarbonyl(DCR);pentaoxonium;Ruthenium, dodecacarbonyltri-, triangulo;Ruthenium,dodecacarbonyltri-;DODECACARBONYLTRIRUTHENIUM
CAS:15243-33-1
MF:C12O12Ru3
MW:639.33
EINECS:239-287-4
Product Categories:Ru;Classes of Metal Compounds;Ru (Ruthenium) Compounds;Transition Metal Compounds;metal carbonyl complexes
Mol File:15243-33-1.mol
RUTHENIUM CARBONYL Structure
RUTHENIUM CARBONYL Chemical Properties
Melting point 150 °C
storage temp. Inert atmosphere,Room Temperature
solubility Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.
form crystal
color orange
CAS DataBase Reference15243-33-1(CAS DataBase Reference)
EPA Substance Registry SystemRuthenium, dodecacarbonyltri-, triangulo (15243-33-1)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-20-2017/11/20
Safety Statements 24/25
RIDADR 1325
WGK Germany 3
Hazard Note Flammable/Harmful
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 28439000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
RUTHENIUM CARBONYL Usage And Synthesis
Reactions
  1. Catalyst for the conversion of enynes to catechol derivatives.
  2. Catalyst for the intermolecular [2+2+1] cycloaddition of ketones, CO and alkenes or alkynes.
  3. 3-Component couplings.
  4. Reaction of α,β-unsaturated imines with carbon monoxide and alkenes to form β,γ-unsaturated γ-butyroactams.
  5. Ester decarboxylation.
  6. Catalyst for hydroamination and C-H bond activation.
  7. Used in sp3 C-H bond arylation and carbonylation.
  8. Ru/halide catalytic system for C-C bond forming reaction between alkynes and unsaturated carbonyl compounds.
  9. Amination of α-hydroxy amides.
Reactions of 15243-33-1_1
Reactions of 15243-33-1_2
Chemical Propertiesorange plates
UsesA H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).
General DescriptionAtomic number of base material: 44 Ruthenium
RUTHENIUM CARBONYL Preparation Products And Raw materials
Raw materialsruthenium pentacarbonyl-->Trifluoromethanesulfonic acid-->Ruthenium(III) chloride
Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Rhodium(III) 2,4-pentanedionate Tris(triphenylphosphine)rhodiu Ruthenium(II) chloride mesitylene dimer Rhodium(II) acetate dimer Dichloro(p-cymene)ruthenium(II) dimer [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Tris(triphenylphosphine)ruthenium(II) chloride [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Benzeneruthenium(II) chloride dimer Molybdenum hexacarbonyl Tungsten hexacarbonyl TPP Dihydridotris(triphenylphosphine)ruthenium carbonyl Ruthenium RUBIDIUM RUTHENIUM CARBONYL

Email:[email protected] [email protected]
Copyright © 2025 Mywellwork.com All rights reserved.