Valeryl chloride

Valeryl chloride Basic information
Product Name:Valeryl chloride
Synonyms:N-butanecarbonylchloride;valeryl;N-VALERYL CHLORIDE;N-VALEROYL CHLORIDE;N-PENTANOYL CHLORIDE;VACL;VALERYL CHLORIDE;VALERIC ACID CHLORIDE
CAS:638-29-9
MF:C5H9ClO
MW:120.58
EINECS:211-330-1
Product Categories:Acid Halides;Building Blocks;Acid Halides;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;ACID CHLORIDES;Carbonyl Compounds;Organic Building Blocks;638-29-9
Mol File:638-29-9.mol
Valeryl chloride Structure
Valeryl chloride Chemical Properties
Melting point -110 °C
Boiling point 125-127 °C(lit.)
density 1.016 g/mL at 25 °C(lit.)
refractive index n20/D 1.42(lit.)
Fp 91 °F
storage temp. Flammables area
solubility Chloroform (Sparingly), Ethyl Acetate (Slightly)
form Liquid
color Clear colorless to light yellow
Water Solubility decomposes
Sensitive Moisture Sensitive
BRN 506293
Stability:Moisture Sensitive
CAS DataBase Reference638-29-9(CAS DataBase Reference)
NIST Chemistry ReferencePentanoyl chloride(638-29-9)
EPA Substance Registry SystemPentanoyl chloride (638-29-9)
Safety Information
Hazard Codes C
Risk Statements 10-20-35-34
Safety Statements 26-36/37/39-45
RIDADR UN 2502 8/PG 2
WGK Germany 3
RTECS YV9107500
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29159080
MSDS Information
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Valeryl chloride English
SigmaAldrich English
ACROS English
ALFA English
Valeryl chloride Usage And Synthesis
Chemical Propertiesclear colorless to light yellow liquid
UsesValeryl chloride is an intermediate for pharmaceuticals, agrochemicals, surfactants, fragrances, electronic chemicals.
General DescriptionA colorless fuming liquid with a pungent odor. Flash point 74°F. Fumes irritate the eyes and mucous membranes. Corrosive.
Air & Water ReactionsHighly flammable. Fumes in air. Reacts exothermically with water to generate hydrochloric and valeric acids, which are corrosive.
Reactivity ProfileValeryl chloride is acidic. Incompatible with water, with bases, including amines, and with strong oxidizing agents and alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
Health HazardMay cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire HazardFlammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Flammability and ExplosibilityFlammable
Safety ProfileA corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Cl-.
Methylene Chloride 5-Bromovaleryl chloride Calcium chloride Sodium chloride Acetyl chloride Myristoyl chloride Choline chloride Chloroacetyl chloride Tosyl chloride tert-Valeryl chloride Sulfuryl chloride Polyvinyl chloride STEAROYL CHLORIDE Benzoyl chloride Potassium chloride 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile Valeryl chloride Isovaleryl chloride Valeroyl Chloride

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