PENTAMETHYLDISILOXANE

PENTAMETHYLDISILOXANE Basic information
Product Name:PENTAMETHYLDISILOXANE
Synonyms:pentamethyl-disiloxan;PENTAMETHYLDISILOXANE;PENTAMETHYLDISILOXANE 97+%;(Trimethylsiloxy)dimethylsilane;1,1,1,3,3-Pentamethylpropanedisiloxane;2,2,4-Trimethyl-3-oxa-2,4-disilapentane;Trimethylsiloxydimethylsilane;Dimethyl(trimethylsilyloxy)silane
CAS:1438-82-0
MF:C5H16OSi2
MW:148.35
EINECS:215-873-5
Product Categories:Chemical Synthesis;Organometallic Reagents;Organosilicon;Siloxanes
Mol File:1438-82-0.mol
PENTAMETHYLDISILOXANE Structure
PENTAMETHYLDISILOXANE Chemical Properties
Boiling point 86 °C (lit.)
density 0.760 g/mL at 20 °C (lit.)
refractive index n20/D 1.373
Fp -9°C
form clear liquid
color Colorless to Almost colorless
Specific Gravity0.758
Water Solubility Not miscible or difficult to mix in water.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity3: reacts with aqueous base
BRN 1734568
InChIInChI=1S/C5H16OSi2/c1-7(2)6-8(3,4)5/h7H,1-5H3
InChIKeyAOJHDNSYXUZCCE-UHFFFAOYSA-N
SMILES[Si](C)(C)(C)O[SiH](C)C
EPA Substance Registry SystemDisiloxane, pentamethyl- (1438-82-0)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 16-23-24/25
RIDADR UN 1993 3/PG 2
WGK Germany 3
10-21
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
PENTAMETHYLDISILOXANE Usage And Synthesis
UsesPentamethyldisiloxane, is an organosilicon compound used in synthesis of siloxane-polyether copolymer surfactants. Pentamethyldisiloxane can also be used as source of the trimethylsilyl functional group in organic synthesis.
UsesPentamethyldisiloxane is used in the synthesis of siloxane-polyether copolymer surfactants. It is also used as source of trimethylsilyl functional group in organic synthesis.
SynthesisSynthesis_1438-82-0
Take prepared potassium trimethylsilanolate 1.12kg in 2L of anhydrous tetrahydrofuran, was added dropwise with stirring dimethylchlorosilane1kg, dropwise, room temperature reaction 1h, filtered, concentrated, extracted with ether, dried and concentrated to give a high purity of 98% or more of pentamethyl disiloxane 1.2kg.
PENTAMETHYLDISILOXANE Preparation Products And Raw materials
Preparation ProductsDIMETHYLSILANE-->3-AMINOPROPYLPENTAMETHYLDISILOXANE
1,3-BIS(ACETOXYMETHYL)-1,1,3,3-TETRAMETHYLDISILOXANE HEXAPHENYLDISILOXANE 1,3-BIS(3-AMINOPROPYL)TETRAMETHYLDISILOXANE Hexamethyldisiloxane 1,3-DIPHENYL-1,1,3,3-TETRAMETHYLDISILOXANE Octamethyltrisiloxane BIS(BROMOMETHYL)TETRAMETHYLDISILOXANE 1,3-BIS(4-HYDROXYBUTYL)TETRAMETHYLDISILOXANE DODECAMETHYLPENTASILOXANE 1,3-Bis(chloromethyl)-1,1,3,3-tetramethyldisiloxane 1,3-BIS(3-CARBOXYPROPYL)TETRAMETHYLDISILOXANE 2,2,5,5-TETRAMETHYL-2,5-DISILA-1-OXACYCLOPENTANE 1,3-BIS(CARBOMETHOXYPROPYL)TETRAMETHYLDISILOXANE 1,3-BIS(3-GLYCIDOXYPROPYL)TETRAMETHYLDISILOXANE Divinyltetramethyldisiloxane 1,3-BIS(3-CYANOPROPYL)TETRAMETHYLDISILOXANE HEXAETHYLDISILOXANE 3,3-DIPHENYLHEXAMETHYLTRISILOXANE

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