Methyl 3-bromopropionate

Methyl 3-bromopropionate Basic information

Product Name:	Methyl 3-bromopropionate
Synonyms:	3-bromopropanoicacidmethylester;3-bromo-propanoicacimethylester;3-bromo-propionicacimethylester;Methyl 3-bromopropanoate;methyl3-bromopropanoate;Propionic acid, 3-bromo-, methyl ester;METHYL 3-BROMOPROPIONATE;METHYL BETA-BROMOPROPIONATE
CAS:	3395-91-3
MF:	C4H7BrO2
MW:	167
EINECS:	222-247-5
Product Categories:	Building Blocks;C2 to C5;Organics;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;C2 to C5;Carbonyl Compounds;Esters;bc0001
Mol File:	3395-91-3.mol

Methyl 3-bromopropionate Chemical Properties

Melting point	75°C
Boiling point	64-66 °C/18 mmHg (lit.)
density	1.53 g/mL at 25 °C (lit.)
refractive index	n20/D 1.458(lit.)
Fp	167 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	Liquid
color	Clear colorless to slightly yellow
Water Solubility	Immiscible
BRN	1742949
CAS DataBase Reference	3395-91-3(CAS DataBase Reference)
NIST Chemistry Reference	Propanoic acid, 3-bromo-, methyl ester(3395-91-3)
EPA Substance Registry System	Propanoic acid, 3-bromo-, methyl ester (3395-91-3)

Safety Information

Hazard Codes	Xn
Risk Statements	22-36/37/38
Safety Statements	26-37/39-24/25
WGK Germany	3
RTECS	UA2451790
TSCA	Yes
HS Code	29159080

MSDS Information

Provider	Language
Methyl 3-bromopropionate	English
SigmaAldrich	English
ACROS	English
ALFA	English

Methyl 3-bromopropionate Usage And Synthesis

Chemical Properties	Very slightly yellow liquid
Uses	Methyl 3-bromopropionate was used in the synthesis of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-l-oxaspiro[n,m]alkan-2-ones.

Methyl 3-bromopropionate Preparation Products And Raw materials

Raw materials	1-Bromo-2-methoxyethane-->Methyl 3-methoxypropionate
Preparation Products	Methyl 3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl) propionate-->METHYL 4-NITROBUTYRATE-->4-BroMo-2-Methylbutan-2-ol-->METHYL 4-ACETYL-5-OXOHEXANOATE

ETHYL 3-BROMOBUTYRATE ETHYL 2,3-DIBROMO-3-PHENYLPROPIONATE DIETHYL (2S,3S)-2-BROMO-3-HYDROXYSUCCINATE 3-BROMOMETHYL-7-METHOXY-1,4-BENZOXAZIN-2-ONE Ethyl 3-bromo-2-(bromomethyl)propionate METHYL 3-BROMO-2,4-DIOXO-4-PHENYLBUTANOATE ETHYL 3-BROMOISOBUTYRATE Methyl 2-(bromomethyl)acrylate Methyl 3-bromobutyrate ETHYL B-BROMOCAPROATE ETHYL 3-BROMOPROPIONATE, [2,3-14C] (S)-(-)-3-BROMOISOBUTYRIC ACID METHYL ESTER Ethyl 2,3-dibromopropionate Ethyl 3-bromopropionate METHYL 3-BROMO-2-(BROMOMETHYL)PROPIONATE Methyl 2,3-dibromopropionate DIMETHYL 2,3-DIBROMO-1,4-BUTANEDIOATE Methyl 3-bromopropionate

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